Synthesis and Spectroscopic Characterization of Some New Axially Ligated Indium(III) Macrocyclic Complexes and Their Biological Activities
المؤلفون المشاركون
Ahmed, Altaf
Bajju, Gauri Devi
Kapahi, Ashu
Devi, Geeta
Gupta, Deepmala
المصدر
Bioinorganic Chemistry and Applications
العدد
المجلد 2014، العدد 2014 (31 ديسمبر/كانون الأول 2014)، ص ص. 1-7، 7ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2014-07-21
دولة النشر
مصر
عدد الصفحات
7
التخصصات الرئيسية
الملخص EN
The synthesis and spectroscopic characterization of new axially ligated indium(III) porphyrin complexes were reported.
Chloroindium(III) porphyrin (TPPIn-Cl) was obtained in good yield by treating the corresponding free base with indium trichloride.
The action of the different phenols on chloroderivatives (TPPIn-Cl) led to the corresponding phenolato complexes (TPPIn-X).
These derivatives were characterized on the basis of mass spectrometry, 1H-NMR, IR, and UV-visible data.
The separation and isolation of these derivatives have been achieved through chromatography.
The spectral properties of free base porphyrin and its corresponding metallated and axially ligated indium(III) porphyrin compounds were compared with each other.
A detailed analysis of UV-Vis, 1H-NMR, and IR suggested the transformation from free base porphyrin to indium(III) porphyrin.
Besides, 13C-NMR and fluorescence spectra were also reported and interpreted.
The stability of these derivatives has also been studied through thermogravimetry.
The complexes were also screened for anticancerous activities.
Among all the complexes, 4-MePhO-InTPP shows highest anticancerous activity.
The title complexe, TPPIn-X (where X = different phenolates), represents a five-coordinate indium(III) porphyrin complex in a square-pyramidal geometry with the phenolate anion as the axial ligand.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Bajju, Gauri Devi& Ahmed, Altaf& Gupta, Deepmala& Kapahi, Ashu& Devi, Geeta. 2014. Synthesis and Spectroscopic Characterization of Some New Axially Ligated Indium(III) Macrocyclic Complexes and Their Biological Activities. Bioinorganic Chemistry and Applications،Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-504572
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Bajju, Gauri Devi…[et al.]. Synthesis and Spectroscopic Characterization of Some New Axially Ligated Indium(III) Macrocyclic Complexes and Their Biological Activities. Bioinorganic Chemistry and Applications No. 2014 (2014), pp.1-7.
https://search.emarefa.net/detail/BIM-504572
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Bajju, Gauri Devi& Ahmed, Altaf& Gupta, Deepmala& Kapahi, Ashu& Devi, Geeta. Synthesis and Spectroscopic Characterization of Some New Axially Ligated Indium(III) Macrocyclic Complexes and Their Biological Activities. Bioinorganic Chemistry and Applications. 2014. Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-504572
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-504572
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر