Bromo-catalyzed photo esterification of benzylsilanes with alcohols under aerobic conditions

المؤلفون المشاركون

Sun, Jing
Ding, Aishun
Gu, Guangxin
Xie, Ruixia

المصدر

Journal of Saudi Chemical Society

العدد

المجلد 21، العدد 2 (28 فبراير/شباط 2017)، ص ص. 245-249، 5ص.

الناشر

الجمعية الكيميائية السعودية

تاريخ النشر

2017-02-28

دولة النشر

السعودية

عدد الصفحات

5

التخصصات الرئيسية

الكيمياء

الموضوعات

الملخص EN

A photoinduced esterification reaction has been developed.

In this reaction, benzylsilane shows very nice reactivity and selectivity, affording the corresponding esters as the only products.

Under photo irradiation, the highly active bromo radical can be generated from the pre-catalyst CBr4, which would promote the initial CASi bond cleavage of benzylsilane via single electron transfer and the final transformation of acetal into ester via proton transfer.

The existence of oxygen can not only oxidize the in situ generated benzyl radical into aldehyde intermediate, but also assist to regenerate bromo radical from bromine anion.

نمط استشهاد جمعية علماء النفس الأمريكية (APA)

Ding, Aishun& Xie, Ruixia& Gu, Guangxin& Sun, Jing. 2017. Bromo-catalyzed photo esterification of benzylsilanes with alcohols under aerobic conditions. Journal of Saudi Chemical Society،Vol. 21, no. 2, pp.245-249.
https://search.emarefa.net/detail/BIM-767207

نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)

Ding, Aishun…[et al.]. Bromo-catalyzed photo esterification of benzylsilanes with alcohols under aerobic conditions. Journal of Saudi Chemical Society Vol. 21, no. 2 (Feb. 2017), pp.245-249.
https://search.emarefa.net/detail/BIM-767207

نمط استشهاد الجمعية الطبية الأمريكية (AMA)

Ding, Aishun& Xie, Ruixia& Gu, Guangxin& Sun, Jing. Bromo-catalyzed photo esterification of benzylsilanes with alcohols under aerobic conditions. Journal of Saudi Chemical Society. 2017. Vol. 21, no. 2, pp.245-249.
https://search.emarefa.net/detail/BIM-767207

نوع البيانات

مقالات

لغة النص

الإنجليزية

الملاحظات

Includes bibliographical references : p. 249

رقم السجل

BIM-767207