![](/images/graphics-bg.png)
Syntheses and characterization of nickel (II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties : Nickel sulphide nanoparticles from a single source precursor
المؤلفون المشاركون
Bobinihi, Felicia F.
Osuntokun, Jejenija
Onwudiwe, Damian C.
المصدر
Journal of Saudi Chemical Society
العدد
المجلد 22، العدد 4 (31 مايو/أيار 2018)، ص ص. 381-395، 15ص.
الناشر
تاريخ النشر
2018-05-31
دولة النشر
السعودية
عدد الصفحات
15
التخصصات الرئيسية
الملخص EN
In this study, ammonium N-benzyldithiocarbamate was synthesized and used to prepare homoleptic Ni(II) bis(N-benzyldithiocarbamate) (1) and heteroleptic Ni(II) complexes involving isocyanate (2) and cyanide (3) ions.
The complexes were characterized by elemental analysis, Fourier transform infra-red (FTIR), and NMR (1H and 13C) spectroscopic techniques.
Complex 2 was further characterized by single crystal X-ray diffraction analysis.
The FTIR showed bidentate coordination for all the complexes as the v(C‚N) stretching frequency were in the 980–1050 cm region without any splitting.
Thermal decomposition profile of the complexes showed decomposition resulting in the formation of nickel sulphides.
The homoleptic complex 1 was utilized as single source precursor (SSP) to prepare Nickel sulphide nanoparticles.
The synthesis of the nanoparticles was conducted using different capping molecules (with various alkyl chain lengths), and at different reaction temperature and time.
Pure phase Heazlewoodite (Ni3S2) nanoparticles were obtained from the X-ray diffraction study.
The TEM analysis showed that the type of capping agent, reaction temperature, and time of reaction have significant effect on the morphology and size of the nanoparticles.
The optical properties of the nanoparticles were studied using absorption and fluorescence spectroscopies, and they displayed evidence of quantum confinement effect.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Bobinihi, Felicia F.& Osuntokun, Jejenija& Onwudiwe, Damian C.. 2018. Syntheses and characterization of nickel (II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties : Nickel sulphide nanoparticles from a single source precursor. Journal of Saudi Chemical Society،Vol. 22, no. 4, pp.381-395.
https://search.emarefa.net/detail/BIM-835382
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Bobinihi, Felicia F.…[et al.]. Syntheses and characterization of nickel (II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties : Nickel sulphide nanoparticles from a single source precursor. Journal of Saudi Chemical Society Vol. 22, no. 4 (May. 2018), pp.381-395.
https://search.emarefa.net/detail/BIM-835382
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Bobinihi, Felicia F.& Osuntokun, Jejenija& Onwudiwe, Damian C.. Syntheses and characterization of nickel (II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties : Nickel sulphide nanoparticles from a single source precursor. Journal of Saudi Chemical Society. 2018. Vol. 22, no. 4, pp.381-395.
https://search.emarefa.net/detail/BIM-835382
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references : p. 395
رقم السجل
BIM-835382
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
![](/images/ebook-kashef.png)
تقوم هذه الخدمة بالتحقق من التشابه أو الانتحال في الأبحاث والمقالات العلمية والأطروحات الجامعية والكتب والأبحاث باللغة العربية، وتحديد درجة التشابه أو أصالة الأعمال البحثية وحماية ملكيتها الفكرية. تعرف اكثر
![](/images/kashef-image.png)