Synthesisand spectral studies of new schiff base pyrimidine-2-ylimino-acetic acid and its complexes with cobalt (II), nickel (II), copper (II), cadmium (II), mercucry (II) and lead (II) ions
Joint Authors
Shihab, Jasim Shihab Sultan
al-Waswi, Falih Hasan Musa Muhammad
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2012, Issue 48 (31 Dec. 2012), pp.466-481, 16 p.
Publisher
University of Babylon College of Sciences
Publication Date
2012-12-31
Country of Publication
Iraq
No. of Pages
16
Main Subjects
Abstract AR
مفاعلة بريميدين -2- يل أمين مع حامض الكلايكوسيلك في وسط الايثانول معطيا ليكاند شيف جديد بريميدين -2- يل ايمينو حامض الخليك (L) تم تشخيصه بتحليل الكاربون, النتروجين, الهيدروجين, طيف تحت الامتصاص الذري, طيف تحت الحمراء, التوصيلية, الخاصية المغناطيسية و البنفسجية - المرئية. تكون أيونات الكوبلت, الكادميوم, الزئبق و الرصاص الثنائية التكافؤ في كل معقداتها رباعية التناسق في شكل هرم رباعي السطوح.
أما أيونات النيكل و النحاس الثنائية التكافؤ في معقداتها فهي سداسية التناسق على شكل ثماني السطوح.
Abstract EN
Pyrimidine-2-ylamine condens with glyoxylic acid gave pyrimidine-2-ylimino-acetic acid (L) and characterized by elemental analysis (C.H.N), FT-IR and 1H, 13C-NMR.
The ligand (L) reacted with metal ions (II) ; Co, Ni, Cu, Cd, Hg and Pb forming complexes.
These complexes were identified by metal analysis (A.A.), FT-IR spectral, conductivity, magnetic susceptibility measurements and UV-visible spectral.
The Co (II), Cd (II), Hg (II) and Pb (II) ions in each complexes are tetra coordinated in a tetrahedral geometry.
The Ni (II), and Cu (II) ions are hexa coordinated in a octahedral geometry.
American Psychological Association (APA)
Shihab, Jasim Shihab Sultan& al-Waswi, Falih Hasan Musa Muhammad. 2012. Synthesisand spectral studies of new schiff base pyrimidine-2-ylimino-acetic acid and its complexes with cobalt (II), nickel (II), copper (II), cadmium (II), mercucry (II) and lead (II) ions. Iraqi National Journal of Chemistry،Vol. 2012, no. 48, pp.466-481.
https://search.emarefa.net/detail/BIM-320997
Modern Language Association (MLA)
Shihab, Jasim Shihab Sultan& al-Waswi, Falih Hasan Musa Muhammad. Synthesisand spectral studies of new schiff base pyrimidine-2-ylimino-acetic acid and its complexes with cobalt (II), nickel (II), copper (II), cadmium (II), mercucry (II) and lead (II) ions. Iraqi National Journal of Chemistry No. 48 (Dec. 2012), pp.466-481.
https://search.emarefa.net/detail/BIM-320997
American Medical Association (AMA)
Shihab, Jasim Shihab Sultan& al-Waswi, Falih Hasan Musa Muhammad. Synthesisand spectral studies of new schiff base pyrimidine-2-ylimino-acetic acid and its complexes with cobalt (II), nickel (II), copper (II), cadmium (II), mercucry (II) and lead (II) ions. Iraqi National Journal of Chemistry. 2012. Vol. 2012, no. 48, pp.466-481.
https://search.emarefa.net/detail/BIM-320997
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 480-481
Record ID
BIM-320997