Rovibrational Interaction and Vibrational Constants of the Symmetric Top Molecule 14NF3
Author
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-05-23
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Medicine
Information Technology and Computer Science
Abstract EN
Several accurate experimental values of the αC and αB rotation-vibration interaction parameters and ωi, xij, and gij vibrational constants have been extracted from the most recent high-resolution Fourier transform infrared, millimeter wave, and centimeter wave investigations in the spectra of the oblate symmetric top molecule 14NF3.
The band-centres used are those of the four fundamental, the overtones, the combination, and hot bands identified in the region between 400 cm−1 and 2000 cm−1.
Comparison of our constants with the ones measured previously, by infrared spectroscopy at low resolution, reveals orders of magnitude higher accuracy of the new values.
The agreement between our values and those determined by ab initio calculations employing the TZ2Pf basis is excellent.
American Psychological Association (APA)
Najib, Hamid. 2013. Rovibrational Interaction and Vibrational Constants of the Symmetric Top Molecule 14NF3. The Scientific World Journal،Vol. 2013, no. 2013, pp.1-5.
https://search.emarefa.net/detail/BIM-1012928
Modern Language Association (MLA)
Najib, Hamid. Rovibrational Interaction and Vibrational Constants of the Symmetric Top Molecule 14NF3. The Scientific World Journal No. 2013 (2013), pp.1-5.
https://search.emarefa.net/detail/BIM-1012928
American Medical Association (AMA)
Najib, Hamid. Rovibrational Interaction and Vibrational Constants of the Symmetric Top Molecule 14NF3. The Scientific World Journal. 2013. Vol. 2013, no. 2013, pp.1-5.
https://search.emarefa.net/detail/BIM-1012928
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1012928