![](/images/graphics-bg.png)
Synthesis of Imine-Naphthol Tripodal Ligand and Study of Its Coordination Behaviour towards Fe(III), Al(III), and Cr(III) Metal Ions
Joint Authors
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-09-08
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
A hexadentate Schiff base tripodal ligand is synthesized by the condensation of tris (2-aminoethyl) amine with 2-hydroxy-1-naphthaldehyde and characterized by various spectroscopic techniques like UV-VIS, IR, NMR, MASS, and elemental analysis.
The solution studies by potentiometric and spectrophotometric methods are done at 25 ± 1°C, µ = 0.1 M KCl, to calculate the protonation constants of the ligand and formation constants of metal complexes formed by the ligand with Fe(III), Al(III), and Cr(III) metal ions.
The affinity of the ligand towards Fe(III) is compared with deferiprone (a drug applied for iron intoxication) and transferrin (the main Fe(III) binding protein in plasma).
Structural analysis of the ligand and the metal complexes was done using semiempirical PM6 method.
Electronic and IR spectra are calculated by semiempirical methods and compared with experimental one.
American Psychological Association (APA)
Kaur, Kirandeep& Baral, Minati. 2014. Synthesis of Imine-Naphthol Tripodal Ligand and Study of Its Coordination Behaviour towards Fe(III), Al(III), and Cr(III) Metal Ions. Bioinorganic Chemistry and Applications،Vol. 2014, no. 2014, pp.1-10.
https://search.emarefa.net/detail/BIM-1016082
Modern Language Association (MLA)
Kaur, Kirandeep& Baral, Minati. Synthesis of Imine-Naphthol Tripodal Ligand and Study of Its Coordination Behaviour towards Fe(III), Al(III), and Cr(III) Metal Ions. Bioinorganic Chemistry and Applications No. 2014 (2014), pp.1-10.
https://search.emarefa.net/detail/BIM-1016082
American Medical Association (AMA)
Kaur, Kirandeep& Baral, Minati. Synthesis of Imine-Naphthol Tripodal Ligand and Study of Its Coordination Behaviour towards Fe(III), Al(III), and Cr(III) Metal Ions. Bioinorganic Chemistry and Applications. 2014. Vol. 2014, no. 2014, pp.1-10.
https://search.emarefa.net/detail/BIM-1016082
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1016082