Broadband Near-Infrared Quantum Cutting in Metal-Ion Codoped Y3Al5O12 Thin Films Grown by Pulsed-Laser Deposition for Solar Cell Application

Abstract EN

We have deposited thin films of yttrium aluminum garnet (YAG) doped with Ce3+ and Yb3+ on quartz and silicon substrates by pulsed laser deposition.

Near-infrared (NIR) quantum cutting which involves the emission of NIR photons through the downconversion from Ce3+ to Yb3+ is realized.

Upon the broadband excitation of Ce3+ ions with a visible photon at the peak wavelength of 450 nm, NIR photons are generated by Yb3+ ions, with an emission wavelength centered at 1030 nm.

The luminescent decay curves of Ce3+ were recorded as a supporting evidence corresponding to the energy transfer.

This work offers a better and more convenient approach compatible with crystalline silicon solar cell compared to conventional bulk phosphors.