Sonochemical Synthesis, Characterization, and Photocatalytic Activity of N-Doped TiO2 Nanocrystals with Mesoporous Structure

Abstract EN

N-Doped TiO2 nanocrystals were synthesized via a simple sonochemical route, using titanium tetrachloride, aqueous ammonia, and urea as starting materials.

The as-synthesized samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) equipped with an energy dispersion X-ray spectrometer (EDS), transmission electron microscopy (TEM), UV-vis diffuse reflection spectroscopy, Raman spectroscopy, and nitrogen adsorption-desorption isotherms.

The results of TEM and nitrogen adsorption-desorption showed that the average size and specific surface area of the as-synthesized nanocrystals are 10 nm and 107.2 m2/g, respectively.

Raman spectral characterization combined with the results of XRD and EDS revealed that N dopant ions were successfully doped into TiO2.

Compared with pure TiO2, the adsorption band edge of N-doped TiO2 samples exhibited an obvious red shift to visible region.

The photocatalytic activities were evaluated by the degradation of Rhodamine B (RhB) under visible light, and the results showed that the N-doped TiO2 sample synthesized by an optimal amount of urea exhibited excellent photocatalytic activity due to its special mesoporous structure and the incorporation of nitrogen dopant ions.