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Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions
Joint Authors
Khan, M. Niyaz
Sim, Yoke-Leng
Ariffin, Azhar
Source
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-01-16
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Medicine
Information Technology and Computer Science
Abstract EN
The values of pseudo-first-order rate constants (kobs) for alkaline hydrolysis of 1, obtained at 1.0 mM NaOH and within CmEnT (total concentration of CmEn) range of 3.0–5.0 mM for C12E23 and 10–20 mM for C18E20, fail to obey pseudophase micellar (PM) model.
The values of the fraction of near irreversible CmEn micellar trapped 1 molecules (FIT1) vary in the range ~0–0.75 for C12E23 and ~0–0.83 for C18E20 under such conditions.
The values of FIT1 become 1.0 at ≥10 mM C12E23 and 50 mM C18E20.
Kinetic analysis of the observed data at ≥10 mM C12E23 shows near irreversible micellar entrapment of 1 molecules under such conditions.
American Psychological Association (APA)
Khan, M. Niyaz& Sim, Yoke-Leng& Ariffin, Azhar. 2014. Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions. The Scientific World Journal،Vol. 2014, no. 2014, pp.1-6.
https://search.emarefa.net/detail/BIM-1050245
Modern Language Association (MLA)
Khan, M. Niyaz…[et al.]. Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions. The Scientific World Journal No. 2014 (2014), pp.1-6.
https://search.emarefa.net/detail/BIM-1050245
American Medical Association (AMA)
Khan, M. Niyaz& Sim, Yoke-Leng& Ariffin, Azhar. Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions. The Scientific World Journal. 2014. Vol. 2014, no. 2014, pp.1-6.
https://search.emarefa.net/detail/BIM-1050245
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1050245