Characteristics of Polyaniline Cobalt Supported Catalysts for Epoxidation Reactions
Joint Authors
Kowalski, Grzegorz
Pielichowski, Jan
Grzesik, Mirosław
Source
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-02-18
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Medicine
Information Technology and Computer Science
Abstract EN
A study of polyaniline (PANI) doping with various cobalt compounds, that is, cobalt(II) chloride, cobalt(II) acetate, and cobalt(II) salen, is presented.
The catalysts were prepared by depositing cobalt compounds onto the polymer surface.
PANI powders containing cobalt ions were obtained by one- or two-step method suspending PANI in the following acetonitrile/acetic acid solution or acetonitrile and then acetic acid solution.
Moreover different ratios of Co(II) : PANI were studied.
Catalysts obtained with both methods and at all ratios were investigated using various techniques including AAS and XPS spectroscopy.
The optimum conditions for preparation of PANI/Co catalysts were established.
Catalytic activity of polyaniline cobalt(II) supported catalysts was tested in dec-1-ene epoxidation with molecular oxygen at room temperature.
The relationship between the amount of cobalt species, measured with both AAS and XPS techniques, and the activity of PANI-Co catalysts has been established.
American Psychological Association (APA)
Kowalski, Grzegorz& Pielichowski, Jan& Grzesik, Mirosław. 2014. Characteristics of Polyaniline Cobalt Supported Catalysts for Epoxidation Reactions. The Scientific World Journal،Vol. 2014, no. 2014, pp.1-9.
https://search.emarefa.net/detail/BIM-1050496
Modern Language Association (MLA)
Kowalski, Grzegorz…[et al.]. Characteristics of Polyaniline Cobalt Supported Catalysts for Epoxidation Reactions. The Scientific World Journal No. 2014 (2014), pp.1-9.
https://search.emarefa.net/detail/BIM-1050496
American Medical Association (AMA)
Kowalski, Grzegorz& Pielichowski, Jan& Grzesik, Mirosław. Characteristics of Polyaniline Cobalt Supported Catalysts for Epoxidation Reactions. The Scientific World Journal. 2014. Vol. 2014, no. 2014, pp.1-9.
https://search.emarefa.net/detail/BIM-1050496
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1050496