Microwave-Promoted Synthesis of Sulfonated Metallophthalocyanines and Aggregation in Different Solvents
Joint Authors
Cui, Na
Zhang, Hongxiao
Zhu, Lijun
Xia, Daohong
Cheng, Zhenhua
Jiang, Shengjuan
Source
Advances in Materials Science and Engineering
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-07-15
Country of Publication
Egypt
No. of Pages
6
Abstract EN
Five metallosulfophthalocyanines (Fe, Ni, Zn, Co, and Cu) compounds were synthesized by microwave irradiation.
Compared to the conventional method of synthesis in terms of reaction time and yields, the microwave-promoted synthesis is preferred with high product yield and short reaction time.
All synthesized products were characterized with MALDI-TOF mass spectrum, Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), and X-ray diffraction (XRD).
Aggregation behavior of the five metallosulfophthalocyanines (MSPc) in different solvents was studied by UV-Vis spectroscopy separately in N,N-dimethyl formamide (DMF) and NaOH aqueous solution (5%wt).
A redshift of maximum absorption wavelength and deviations from Lambert-Beer law with increasing the concentration were observed.
The dimerization equilibrium constants (K) of the five MSPc were determined, respectively.
American Psychological Association (APA)
Cheng, Zhenhua& Cui, Na& Jiang, Shengjuan& Zhang, Hongxiao& Zhu, Lijun& Xia, Daohong. 2015. Microwave-Promoted Synthesis of Sulfonated Metallophthalocyanines and Aggregation in Different Solvents. Advances in Materials Science and Engineering،Vol. 2015, no. 2015, pp.1-6.
https://search.emarefa.net/detail/BIM-1053104
Modern Language Association (MLA)
Cheng, Zhenhua…[et al.]. Microwave-Promoted Synthesis of Sulfonated Metallophthalocyanines and Aggregation in Different Solvents. Advances in Materials Science and Engineering No. 2015 (2015), pp.1-6.
https://search.emarefa.net/detail/BIM-1053104
American Medical Association (AMA)
Cheng, Zhenhua& Cui, Na& Jiang, Shengjuan& Zhang, Hongxiao& Zhu, Lijun& Xia, Daohong. Microwave-Promoted Synthesis of Sulfonated Metallophthalocyanines and Aggregation in Different Solvents. Advances in Materials Science and Engineering. 2015. Vol. 2015, no. 2015, pp.1-6.
https://search.emarefa.net/detail/BIM-1053104
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1053104