Synthesis of CuNiC and CuNiγ-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction
Joint Authors
Lortie, Maxime
Isaifan, Rima
Liu, Yun
Mommers, Sander
Source
International Journal of Chemical Engineering
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-03-22
Country of Publication
Egypt
No. of Pages
9
Abstract EN
A new polyol synthesis method is described in which CuNi nanoparticles of different Cu/Ni atomic ratios were supported on both carbon and gamma-alumina and compared with Pt catalysts using the reverse water gas shift, RWGS, reaction.
All catalysts were highly selective for CO formation.
The concentration of CH4 was less than the detection limit.
Cu was the most abundant metal on the CuNi alloy surfaces, as determined by X-ray photoelectron spectroscopy, XPS, measurements.
Only one CuNi alloy catalyst, Cu50Ni50/C, appeared to be as thermally stable as the Pt/C catalysts.
After three temperature cycles, from 400 to 700°C, the CO yield at 700°C obtained using the Cu50Ni50/C catalyst was comparable to that obtained using a Pt/C catalyst.
American Psychological Association (APA)
Lortie, Maxime& Isaifan, Rima& Liu, Yun& Mommers, Sander. 2015. Synthesis of CuNiC and CuNiγ-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction. International Journal of Chemical Engineering،Vol. 2015, no. 2015, pp.1-9.
https://search.emarefa.net/detail/BIM-1065396
Modern Language Association (MLA)
Lortie, Maxime…[et al.]. Synthesis of CuNiC and CuNiγ-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction. International Journal of Chemical Engineering No. 2015 (2015), pp.1-9.
https://search.emarefa.net/detail/BIM-1065396
American Medical Association (AMA)
Lortie, Maxime& Isaifan, Rima& Liu, Yun& Mommers, Sander. Synthesis of CuNiC and CuNiγ-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction. International Journal of Chemical Engineering. 2015. Vol. 2015, no. 2015, pp.1-9.
https://search.emarefa.net/detail/BIM-1065396
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1065396