New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties
Joint Authors
Nunes, Marcelo Carpes
Ribeiro, Marcos Antonio
Nunes, Fábio Souza
Source
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-12-21
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The polynuclear complexes [Mo3O8(tidf)]·dmso·2H2O (1) and [{Cu2(tidf)}2(μ-Mo8O24)] (2) (tidf2− is a symmetrical tetraiminodiphenolate Robson-type macrocyclic ligand) were prepared from equimolar combinations of [Mg2(tidf)](NO3)2·4H2O, [MoO2Cl2(dmso)2] (for 1) and complex 1 and Cu(ClO4)2·4H2O (for 2) in acetonitrile.
Molecular structures of both complexes were determined and showed atypical modes of coordination.
A significant observation was the remarkable flexibility of the macrocycle ligand that effectively accommodated the steric demands of metal cations and the packing forces and showed a unique mode of coordination.
Spectroscopic (UV-vis and FTIR) and redox properties are discussed.
American Psychological Association (APA)
Nunes, Marcelo Carpes& Ribeiro, Marcos Antonio& Nunes, Fábio Souza. 2015. New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties. Journal of Chemistry،Vol. 2015, no. 2015, pp.1-9.
https://search.emarefa.net/detail/BIM-1067491
Modern Language Association (MLA)
Nunes, Marcelo Carpes…[et al.]. New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties. Journal of Chemistry No. 2015 (2015), pp.1-9.
https://search.emarefa.net/detail/BIM-1067491
American Medical Association (AMA)
Nunes, Marcelo Carpes& Ribeiro, Marcos Antonio& Nunes, Fábio Souza. New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties. Journal of Chemistry. 2015. Vol. 2015, no. 2015, pp.1-9.
https://search.emarefa.net/detail/BIM-1067491
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1067491