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Synthesis and Preliminary Characterization of a PPE-Type Polymer Containing Substituted Fullerenes and Transition Metal Ligation Sites
Joint Authors
Walters, Keith A.
Basinger, Corinne A.
Sullivan, Kaitlin
Siemer, Sarah
Oehrle, Stuart A.
Source
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-11-05
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
A substituted fullerene was incorporated into a PPE-conjugated polymer repeat unit.
This subunit was then polymerized via Sonogashira coupling with other repeat units to create polymeric systems approaching 50 repeat units (based on GPC characterization).
Bipyridine ligands were incorporated into some of these repeat units to provide sites for transition metal coordination.
Photophysical characterization of the absorption and emission properties of these systems shows excited states located on both the fullerene and aromatic backbone of the polymers that exist in a thermally controlled equilibrium.
Future work will explore other substituted polyaromatic systems using similar methodologies.
American Psychological Association (APA)
Basinger, Corinne A.& Sullivan, Kaitlin& Siemer, Sarah& Oehrle, Stuart A.& Walters, Keith A.. 2015. Synthesis and Preliminary Characterization of a PPE-Type Polymer Containing Substituted Fullerenes and Transition Metal Ligation Sites. Journal of Chemistry،Vol. 2015, no. 2015, pp.1-11.
https://search.emarefa.net/detail/BIM-1067572
Modern Language Association (MLA)
Basinger, Corinne A.…[et al.]. Synthesis and Preliminary Characterization of a PPE-Type Polymer Containing Substituted Fullerenes and Transition Metal Ligation Sites. Journal of Chemistry No. 2015 (2015), pp.1-11.
https://search.emarefa.net/detail/BIM-1067572
American Medical Association (AMA)
Basinger, Corinne A.& Sullivan, Kaitlin& Siemer, Sarah& Oehrle, Stuart A.& Walters, Keith A.. Synthesis and Preliminary Characterization of a PPE-Type Polymer Containing Substituted Fullerenes and Transition Metal Ligation Sites. Journal of Chemistry. 2015. Vol. 2015, no. 2015, pp.1-11.
https://search.emarefa.net/detail/BIM-1067572
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1067572