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Catalytic Hydrodechlorination of Trichlorobenzenes with Pd(Phen)Cl2 as Catalyst Precursor
Joint Authors
Zhang, Guanlin
Xu, Hu
Fan, Yuehui
Wang, Yuhong
Zhang, Lirong
Lu, Guanzhong
Source
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-08-27
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
We reported the catalytic hydrodechlorination (HDC) of trichlorobenzenes by an organometallic compound Pd(Phen)Cl2 as a catalyst precursor.
The catalyst precursor was prepared by chemical coordination reaction and characterized by FTIR and 1H NMR techniques.
The HDC performance of Pd(Phen)Cl2 as catalyst precursor was evaluated on 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzenes (TCBs).
All TCBs could be converted to dechlorination products with high conversion.
Products distribution was closely related with the substrate structures and C-Cl bond energies.
A reasonable reaction mechanism was also proposed.
American Psychological Association (APA)
Zhang, Guanlin& Xu, Hu& Fan, Yuehui& Wang, Yuhong& Zhang, Lirong& Lu, Guanzhong. 2015. Catalytic Hydrodechlorination of Trichlorobenzenes with Pd(Phen)Cl2 as Catalyst Precursor. Journal of Nanomaterials،Vol. 2015, no. 2015, pp.1-8.
https://search.emarefa.net/detail/BIM-1069424
Modern Language Association (MLA)
Zhang, Guanlin…[et al.]. Catalytic Hydrodechlorination of Trichlorobenzenes with Pd(Phen)Cl2 as Catalyst Precursor. Journal of Nanomaterials No. 2015 (2015), pp.1-8.
https://search.emarefa.net/detail/BIM-1069424
American Medical Association (AMA)
Zhang, Guanlin& Xu, Hu& Fan, Yuehui& Wang, Yuhong& Zhang, Lirong& Lu, Guanzhong. Catalytic Hydrodechlorination of Trichlorobenzenes with Pd(Phen)Cl2 as Catalyst Precursor. Journal of Nanomaterials. 2015. Vol. 2015, no. 2015, pp.1-8.
https://search.emarefa.net/detail/BIM-1069424
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1069424