Crystallization Behavior of Phosphate Glasses with Hydrophobic Coating Materials
Joint Authors
Source
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-10-19
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
We analyzed the effect of the addition of Li2O3, TiO2, and Fe2O3 on the crystallization behavior of P2O5–CaO–SiO2–K2O glasses and the effect of the crystallization behavior on the roughness and hydrophobicity of the coated surface.
Exothermic behavior, including a strong exothermic peak in the 833–972 K temperature range when Fe2O3, TiO2, or Li2O3 was added, was confirmed by differential thermal analysis.
The modified glass samples (PFTL1–3) showed diffraction peaks when heated at 1073 and 1123 K for 5 min; the crystallized phase corresponds to Fe3(PO4)2, that is, graftonite.
We confirmed that the intensity of the diffraction peaks increases at high temperatures and with increasing Li2O3 content.
In the case of the PFTL3 glass, a Li3Fe2(PO4)2 phase, that is, trilithium diiron(III) tris[phosphate(V)], was observed.
Through scanning electron microscopy and the contact angles of the surfaces with water, we confirmed that the increase in surface roughness, correlated to the crystallization of the glass frit, increases hydrophobicity of the surface.
The calculated values of the local activation energies for the growth of Fe3(PO4)2 on the PTFL1, PTFL2, and PFTL3 glass were 237–292 kJ mol−1, 182–258 kJ mol−1, and 180–235 kJ mol−1.
American Psychological Association (APA)
Chung, Jaeyeop& Ryu, Bong-Ki. 2015. Crystallization Behavior of Phosphate Glasses with Hydrophobic Coating Materials. Journal of Nanomaterials،Vol. 2015, no. 2015, pp.1-10.
https://search.emarefa.net/detail/BIM-1069500
Modern Language Association (MLA)
Chung, Jaeyeop& Ryu, Bong-Ki. Crystallization Behavior of Phosphate Glasses with Hydrophobic Coating Materials. Journal of Nanomaterials No. 2015 (2015), pp.1-10.
https://search.emarefa.net/detail/BIM-1069500
American Medical Association (AMA)
Chung, Jaeyeop& Ryu, Bong-Ki. Crystallization Behavior of Phosphate Glasses with Hydrophobic Coating Materials. Journal of Nanomaterials. 2015. Vol. 2015, no. 2015, pp.1-10.
https://search.emarefa.net/detail/BIM-1069500
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1069500