Synthesis and Characterization of an Iron Nitride Constructed by a Novel Template of Metal Organic Framework
Joint Authors
Liu, Suyan
Huo, Quan
Han, Yang
Chen, Rongna
Chen, Peipei
Li, Yuan
Source
Issue
Vol. 2015, Issue 2015 (31 Dec. 2015), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2015-08-03
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
An iron nitride with high surface area was synthesized from an iron-based metal organic framework (Fe-MOF) in this work.
During the synthesis process, the Fe-MOF of MIL-53 served as a hard template, a template to impart a certain degree of morphology for iron oxide products and to form porosities for iron nitride products.
Moreover, it played the roles of iron sources for the synthesis of the final iron oxides and the iron nitrides.
The physicochemical properties of the materials were characterized by a series of technologies including XRD, SEM, and N2-adsorption/desorption.
The results showed that the iron nitride synthesized from MIL-53 was α- Fe 2-3 N.
And, the α- Fe 2-3 N showed the morphology with loosely aggregated particles which favored the formation of rich interparticle porosities.
As a result, the surface area of the α- Fe 2-3 N was larger than those of samples using α-Fe2O3 as precursors and its value was 41 m2/g.
In addition, the results agreed that both raw material properties (such as crystallinity and surface areas) and nitriding approaches had significant effects on the surface areas of iron nitrides.
Also the results were proved by the iron oxide synthesized with different methods.
This new synthetic strategy could be a general approach for the preparation of late transition metal nitrides with peculiar properties.
American Psychological Association (APA)
Liu, Suyan& Huo, Quan& Chen, Rongna& Chen, Peipei& Li, Yuan& Han, Yang. 2015. Synthesis and Characterization of an Iron Nitride Constructed by a Novel Template of Metal Organic Framework. Journal of Spectroscopy،Vol. 2015, no. 2015, pp.1-8.
https://search.emarefa.net/detail/BIM-1070284
Modern Language Association (MLA)
Liu, Suyan…[et al.]. Synthesis and Characterization of an Iron Nitride Constructed by a Novel Template of Metal Organic Framework. Journal of Spectroscopy No. 2015 (2015), pp.1-8.
https://search.emarefa.net/detail/BIM-1070284
American Medical Association (AMA)
Liu, Suyan& Huo, Quan& Chen, Rongna& Chen, Peipei& Li, Yuan& Han, Yang. Synthesis and Characterization of an Iron Nitride Constructed by a Novel Template of Metal Organic Framework. Journal of Spectroscopy. 2015. Vol. 2015, no. 2015, pp.1-8.
https://search.emarefa.net/detail/BIM-1070284
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1070284