Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications
Joint Authors
Aldea, Anca
Albu, Ana-Maria
Nicolescu, Alina
Tecuceanu, Victorita
Source
Advances in Materials Science and Engineering
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-08-07
Country of Publication
Egypt
No. of Pages
9
Abstract EN
Two N-substituted amides (N-acryloyl morpholine and N-methyl-N-vinylacetamide) were polymerized in different solvents using radical initiator.
The tacticity of obtained polymers was determined by 400 MHz 1H-NMR and 13C-NMR.
At a given temperature, the syndiotacticity increased with increasing the solvent polarity.
This solvent effect may be related to the hydrogen bonding interaction among solvent, monomer, and/or growing species.
A peculiar aspect regards the steric hindrance at the nitrogen atom.
American Psychological Association (APA)
Aldea, Anca& Albu, Ana-Maria& Nicolescu, Alina& Tecuceanu, Victorita. 2016. Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications. Advances in Materials Science and Engineering،Vol. 2016, no. 2016, pp.1-9.
https://search.emarefa.net/detail/BIM-1096283
Modern Language Association (MLA)
Aldea, Anca…[et al.]. Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications. Advances in Materials Science and Engineering No. 2016 (2016), pp.1-9.
https://search.emarefa.net/detail/BIM-1096283
American Medical Association (AMA)
Aldea, Anca& Albu, Ana-Maria& Nicolescu, Alina& Tecuceanu, Victorita. Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications. Advances in Materials Science and Engineering. 2016. Vol. 2016, no. 2016, pp.1-9.
https://search.emarefa.net/detail/BIM-1096283
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1096283
