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Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand
Joint Authors
Shu, Xu-gang
Wu, Chun-li
Li, Cui-jin
Zhang, Min
Wan, Ke
Wu, Xin
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-02-10
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
The zinc(II) complex (C2H6NS)2Zn·ZnCl2 was synthesized with 2-aminoethanethiol hydrochloride and zinc sulfate heptahydrate as the raw materials in aqueous solution.
The composition and structure of the complex were characterized by elemental analysis, infrared spectra, single crystal X-ray diffraction, and thermogravimetry.
The crystal structure of the zinc(II) complex belongs to monoclinic system, space group P 21/n, with cell parameters of a = 0.84294(4), b = 0.83920(4), c = 1.65787(8) nm, Z=2, and D = 2.041 g/cm3.
In this paper, the interaction of complex with Ct-DNA was investigated by UV-visible and viscosimetric techniques.
Upon addition of the complex, important changes were observed in the characteristic UV-Vis bands (hyperchromism) of calf thymus DNA and some changes in specific viscosity.
The experimental results showed that the complex is bound to DNA intercalative (intercalation binding).
American Psychological Association (APA)
Shu, Xu-gang& Wu, Chun-li& Li, Cui-jin & Zhang, Min& Wan, Ke& Wu, Xin. 2016. Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand. Bioinorganic Chemistry and Applications،Vol. 2016, no. 2016, pp.1-7.
https://search.emarefa.net/detail/BIM-1096786
Modern Language Association (MLA)
Shu, Xu-gang…[et al.]. Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand. Bioinorganic Chemistry and Applications No. 2016 (2016), pp.1-7.
https://search.emarefa.net/detail/BIM-1096786
American Medical Association (AMA)
Shu, Xu-gang& Wu, Chun-li& Li, Cui-jin & Zhang, Min& Wan, Ke& Wu, Xin. Synthesis, Crystal Structure, Spectroscopic Properties, and Interaction with Ct-DNA of Zn(II) with 2-Aminoethanethiol Hydrochloride Ligand. Bioinorganic Chemistry and Applications. 2016. Vol. 2016, no. 2016, pp.1-7.
https://search.emarefa.net/detail/BIM-1096786
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1096786