Gas ChromatographyAtmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal
Joint Authors
Zuber, Jan
Kroll, Marius M.
Rathsack, Philipp
Otto, Matthias
Source
International Journal of Analytical Chemistry
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-03-15
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
Pyrolysis oil from the slow pyrolysis of German brown coal from Schöningen, obtained at a temperature of 500°C, was separated and analyzed using hyphenation of gas chromatography with an atmospheric pressure chemical ionization source operated in negative ion mode and Fourier transform ion cyclotron resonance mass spectrometry (GC-APCI-FT-ICR-MS).
Development of this ultrahigh-resolving analysis method is described, that is, optimization of specific GC and APCI parameters and performed data processing.
The advantages of GC-APCI-FT-ICR-MS hyphenation, for example, soft ionization, ultrahigh-resolving detection, and most important isomer separation, were demonstrated for the sample liquid.
For instance, it was possible to separate and identify nine different propylphenol, ethylmethylphenol, and trimethylphenol isomers.
Furthermore, homologous series of different acids, for example, alkyl and alkylene carboxylic acids, were verified, as well as homologous series of alkyl phenols, alkyl dihydroxy benzenes, and alkoxy alkyl phenols.
American Psychological Association (APA)
Zuber, Jan& Kroll, Marius M.& Rathsack, Philipp& Otto, Matthias. 2016. Gas ChromatographyAtmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. International Journal of Analytical Chemistry،Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1104945
Modern Language Association (MLA)
Zuber, Jan…[et al.]. Gas ChromatographyAtmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. International Journal of Analytical Chemistry No. 2016 (2016), pp.1-12.
https://search.emarefa.net/detail/BIM-1104945
American Medical Association (AMA)
Zuber, Jan& Kroll, Marius M.& Rathsack, Philipp& Otto, Matthias. Gas ChromatographyAtmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal. International Journal of Analytical Chemistry. 2016. Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1104945
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1104945