Noble Metal Decoration and Presulfation on TiO2: Increased Photocatalytic Activity and Efficient Esterification of n-Butanol with Citric Acid
Joint Authors
Niu, Yu
Huang, Pan
Li, Fuying
Yang, Kai
Yang, Jinbei
Wang, Renzhang
Lin, Cheng
Qiu, Ting
Source
International Journal of Photoenergy
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-03-02
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
TiO2 has been widely used as a key catalyst in photocatalytic reactions; it also shows good catalytic activity for esterification reactions.
Different sulfated M-TiO2 nanoparticles (M = Ag, Au, Rh, and Pt) were prepared by photodeposition and ultrasonic methods.
The results show that the noble metal nanoparticles, which were loaded onto a TiO2 surface, slightly affected the crystal phase and particle size of TiO2.
Among all the catalysts, S O 4 2 - /Au-TiO2 exhibited the best catalytic activity in the esterification reaction for the synthesis of citric acid n-butyl acetate and in the decomposition of methyl orange, as confirmed by a high conversion rate of up to 98.2% and 100% degradation rate, respectively.
This can be attributed to an increase in the Lewis acidity of the catalyst and increased separation efficiency of electron-hole pairs.
This superior catalyst has great potential applications in esterification reactions and wastewater treatments.
American Psychological Association (APA)
Niu, Yu& Huang, Pan& Li, Fuying& Yang, Kai& Yang, Jinbei& Wang, Renzhang…[et al.]. 2016. Noble Metal Decoration and Presulfation on TiO2: Increased Photocatalytic Activity and Efficient Esterification of n-Butanol with Citric Acid. International Journal of Photoenergy،Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1106480
Modern Language Association (MLA)
Niu, Yu…[et al.]. Noble Metal Decoration and Presulfation on TiO2: Increased Photocatalytic Activity and Efficient Esterification of n-Butanol with Citric Acid. International Journal of Photoenergy No. 2016 (2016), pp.1-12.
https://search.emarefa.net/detail/BIM-1106480
American Medical Association (AMA)
Niu, Yu& Huang, Pan& Li, Fuying& Yang, Kai& Yang, Jinbei& Wang, Renzhang…[et al.]. Noble Metal Decoration and Presulfation on TiO2: Increased Photocatalytic Activity and Efficient Esterification of n-Butanol with Citric Acid. International Journal of Photoenergy. 2016. Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1106480
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1106480