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Rapid Quantitative Analysis of Forest Biomass Using Fourier Transform Infrared Spectroscopy and Partial Least Squares Regression
Joint Authors
Fasina, O. O.
Via, Brian K.
Acquah, Gifty E.
Eckhardt, Lori G.
Source
Journal of Analytical Methods in Chemistry
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-11-24
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
Fourier transform infrared reflectance (FTIR) spectroscopy has been used to predict properties of forest logging residue, a very heterogeneous feedstock material.
Properties studied included the chemical composition, thermal reactivity, and energy content.
The ability to rapidly determine these properties is vital in the optimization of conversion technologies for the successful commercialization of biobased products.
Partial least squares regression of first derivative treated FTIR spectra had good correlations with the conventionally measured properties.
For the chemical composition, constructed models generally did a better job of predicting the extractives and lignin content than the carbohydrates.
In predicting the thermochemical properties, models for volatile matter and fixed carbon performed very well (i.e., R2 > 0.80, RPD > 2.0).
The effect of reducing the wavenumber range to the fingerprint region for PLS modeling and the relationship between the chemical composition and higher heating value of logging residue were also explored.
This study is new and different in that it is the first to use FTIR spectroscopy to quantitatively analyze forest logging residue, an abundant resource that can be used as a feedstock in the emerging low carbon economy.
Furthermore, it provides a complete and systematic characterization of this heterogeneous raw material.
American Psychological Association (APA)
Acquah, Gifty E.& Via, Brian K.& Fasina, O. O.& Eckhardt, Lori G.. 2016. Rapid Quantitative Analysis of Forest Biomass Using Fourier Transform Infrared Spectroscopy and Partial Least Squares Regression. Journal of Analytical Methods in Chemistry،Vol. 2016, no. 2016, pp.1-10.
https://search.emarefa.net/detail/BIM-1107272
Modern Language Association (MLA)
Acquah, Gifty E.…[et al.]. Rapid Quantitative Analysis of Forest Biomass Using Fourier Transform Infrared Spectroscopy and Partial Least Squares Regression. Journal of Analytical Methods in Chemistry No. 2016 (2016), pp.1-10.
https://search.emarefa.net/detail/BIM-1107272
American Medical Association (AMA)
Acquah, Gifty E.& Via, Brian K.& Fasina, O. O.& Eckhardt, Lori G.. Rapid Quantitative Analysis of Forest Biomass Using Fourier Transform Infrared Spectroscopy and Partial Least Squares Regression. Journal of Analytical Methods in Chemistry. 2016. Vol. 2016, no. 2016, pp.1-10.
https://search.emarefa.net/detail/BIM-1107272
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1107272