Electrochemical and Mechanical Failure of Graphite-Based Anode Materials in Li-Ion Batteries for Electric Vehicles
Joint Authors
Lin, Cheng
Tang, Aihua
Wu, Ningning
Xing, Jilei
Source
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-10-16
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
Graphite-based anode materials undergo electrochemical reactions, coupling with mechanical degradation during battery operation, can affect or deteriorate the performance of Li-ion batteries dramatically, and even lead to the battery failure in electric vehicle.
First, a single particle model (SPM) based on kinetics of electrochemical reactions was built in this paper.
Then the Li-ion concentration and evolution of diffusion induced stresses (DISs) within the SPM under galvanostatic operating conditions were analyzed by utilizing a mathematical method.
Next, evolution of stresses or strains in the SPM, together with mechanical degradation of anode materials, was elaborated in detail.
Finally, in order to verify the hypothesis aforementioned surface and morphology of the graphite-based anode dismantled from fresh and degraded cells after galvanostatic charge/discharge cycling were analyzed by X-ray diffraction (XRD), field-emission scanning electron microscopy (SEM), and transmission electron microscopy (TEM).
The results show that large volume changes of anode materials caused DISs during Li-ion insertion and extraction within the active particles.
The continuous accumulations of DISs brought about mechanical failure of the anode eventually.
American Psychological Association (APA)
Lin, Cheng& Tang, Aihua& Wu, Ningning& Xing, Jilei. 2016. Electrochemical and Mechanical Failure of Graphite-Based Anode Materials in Li-Ion Batteries for Electric Vehicles. Journal of Chemistry،Vol. 2016, no. 2016, pp.1-7.
https://search.emarefa.net/detail/BIM-1107618
Modern Language Association (MLA)
Lin, Cheng…[et al.]. Electrochemical and Mechanical Failure of Graphite-Based Anode Materials in Li-Ion Batteries for Electric Vehicles. Journal of Chemistry No. 2016 (2016), pp.1-7.
https://search.emarefa.net/detail/BIM-1107618
American Medical Association (AMA)
Lin, Cheng& Tang, Aihua& Wu, Ningning& Xing, Jilei. Electrochemical and Mechanical Failure of Graphite-Based Anode Materials in Li-Ion Batteries for Electric Vehicles. Journal of Chemistry. 2016. Vol. 2016, no. 2016, pp.1-7.
https://search.emarefa.net/detail/BIM-1107618
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1107618