Synthesis of Novel Derivatives of Carbazole-Thiophene, Their Electronic Properties, and Computational Studies
Joint Authors
Sulaiman, Khaulah
Ariffin, Azhar
Damit, E. F.
Nordin, N.
Source
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-14, 14 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-05-10
Country of Publication
Egypt
No. of Pages
14
Main Subjects
Abstract EN
A series of carbazole-thiophene dimers, P1–P9, were synthesized using Suzuki-Miyaura and Ullmann coupling reactions.
In P1–P9, carbazole-thiophenes were linked at the N-9 position for different core groups via biphenyl, dimethylbiphenyl, and phenyl.
Electronic properties were evaluated by UV-Vis, cyclic voltammogram, and theoretical calculations.
Particularly, the effects of conjugation connectivity on photophysical and electrochemical properties, as well as the correlation between carbazole-thiophene and the core, were studied.
Carbazole connecting with thiophenes at the 3,6-positions and the phenyl group as a core group leads to increased stabilization of HOMO and LUMO energy levels where the bandgap ( Δ E ) is significantly reduced.
American Psychological Association (APA)
Damit, E. F.& Nordin, N.& Ariffin, Azhar& Sulaiman, Khaulah. 2016. Synthesis of Novel Derivatives of Carbazole-Thiophene, Their Electronic Properties, and Computational Studies. Journal of Chemistry،Vol. 2016, no. 2016, pp.1-14.
https://search.emarefa.net/detail/BIM-1107807
Modern Language Association (MLA)
Damit, E. F.…[et al.]. Synthesis of Novel Derivatives of Carbazole-Thiophene, Their Electronic Properties, and Computational Studies. Journal of Chemistry No. 2016 (2016), pp.1-14.
https://search.emarefa.net/detail/BIM-1107807
American Medical Association (AMA)
Damit, E. F.& Nordin, N.& Ariffin, Azhar& Sulaiman, Khaulah. Synthesis of Novel Derivatives of Carbazole-Thiophene, Their Electronic Properties, and Computational Studies. Journal of Chemistry. 2016. Vol. 2016, no. 2016, pp.1-14.
https://search.emarefa.net/detail/BIM-1107807
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1107807