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Protonic Conduction of Nanostructured Y-Doped BaZrO3
Joint Authors
Source
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-12-26
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Nanostructured ionic conductors have recently attracted our attention due to the expectation that they may lead to new functionalities absent in microcrystalline conductors.
In this study, nanostructured barium zirconate with perovskite crystal structure was prepared and its grain and grain boundary protonic conduction was investigated using ac impedance measurements as a function of temperature (RT ~ 400°C) and water partial pressure.
The grain was highly conductive of protons, which is governed by the concentration of protonic defects at all temperatures.
On the other hand, the grain boundary was not the preferred route for protonic conduction due to high resistance.
However, enhanced protonic transport was observed at certain temperatures (<100°C).
The protonic resistivity below that temperature decreased with decreasing temperature, showing positive activation energy in relation to temperature.
The conduction route for the enhanced transport was the serial grain boundary.
In addition, the route was compared with that of nanostructured zirconia with fluorite crystal-structure.
American Psychological Association (APA)
Park, Hee Jung& Roh, Jong Wook. 2016. Protonic Conduction of Nanostructured Y-Doped BaZrO3. Journal of Nanomaterials،Vol. 2016, no. 2016, pp.1-6.
https://search.emarefa.net/detail/BIM-1109466
Modern Language Association (MLA)
Park, Hee Jung& Roh, Jong Wook. Protonic Conduction of Nanostructured Y-Doped BaZrO3. Journal of Nanomaterials No. 2016 (2016), pp.1-6.
https://search.emarefa.net/detail/BIM-1109466
American Medical Association (AMA)
Park, Hee Jung& Roh, Jong Wook. Protonic Conduction of Nanostructured Y-Doped BaZrO3. Journal of Nanomaterials. 2016. Vol. 2016, no. 2016, pp.1-6.
https://search.emarefa.net/detail/BIM-1109466
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1109466