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Speciation in Solutions of Lithium Salts in Dimethyl Sulfoxide, Propylene Carbonate, and Dimethyl Carbonate from Raman Data: A Minireview
Joint Authors
Gorobets, M. I.
Ataev, M. B.
Gafurov, M. M.
Kirillov, S. A.
Source
Issue
Vol. 2016, Issue 2016 (31 Dec. 2016), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2016-11-06
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
Our recent Raman studies of cation and anion solvation and ion pairing in solutions of lithium salts in dimethyl sulfoxide, propylene carbonate, and dimethyl carbonate are briefly overviewed.
Special attention is paid to differences in our and existing data and concepts.
As follows from our results, cation solvation numbers in solutions are low (~2) and disagree with previous measurements.
This discrepancy is shown to arise from correct accounting for dimerization, hydrogen bonding, and conformation equilibria in the solvents disregarded in early studies.
Another disputable question touches upon the absence of free ions in solutions of lithium salts in carbonate solvents and the statement that the charge transfer in carbonate solutions is caused by SSIPs.
Direct proofs of the nature of charge carriers in the solvents studied have been obtained by means of analyses of vibrational dynamics.
It has been found that collision times for free anions are short and evidence weak interactions between anions and solvent molecules.
In SSIPs, collision times are an order of magnitude longer thus signifying strong interactions between anions and cations.
In CIPs, collision times become shorter than in SSIPs reflecting the transformation of the structure of concentrated solutions to that of molten salts.
American Psychological Association (APA)
Gorobets, M. I.& Ataev, M. B.& Gafurov, M. M.& Kirillov, S. A.. 2016. Speciation in Solutions of Lithium Salts in Dimethyl Sulfoxide, Propylene Carbonate, and Dimethyl Carbonate from Raman Data: A Minireview. Journal of Spectroscopy،Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1110796
Modern Language Association (MLA)
Gorobets, M. I.…[et al.]. Speciation in Solutions of Lithium Salts in Dimethyl Sulfoxide, Propylene Carbonate, and Dimethyl Carbonate from Raman Data: A Minireview. Journal of Spectroscopy No. 2016 (2016), pp.1-12.
https://search.emarefa.net/detail/BIM-1110796
American Medical Association (AMA)
Gorobets, M. I.& Ataev, M. B.& Gafurov, M. M.& Kirillov, S. A.. Speciation in Solutions of Lithium Salts in Dimethyl Sulfoxide, Propylene Carbonate, and Dimethyl Carbonate from Raman Data: A Minireview. Journal of Spectroscopy. 2016. Vol. 2016, no. 2016, pp.1-12.
https://search.emarefa.net/detail/BIM-1110796
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1110796