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Multiionic and Permittivity-Related Effects on the Diffuse Electric Double Layer Structure at Solid-Electrolyte Solution Interfaces
Joint Authors
López-García, J. J.
Horno, J.
Grosse, C.
Source
Advances in Materials Science and Engineering
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-09-30
Country of Publication
Egypt
No. of Pages
11
Abstract EN
The structure and differential capacitance of the diffuse part of the electric double layer at solid-electrolyte solution interfaces are examined using a theoretical model that takes into account the finite ion size by modeling the solution as a suspension of polarizable insulating spheres in water.
This formalism is applied to binary and mixed electrolyte solutions using the “Boublik–Mansoori–Carnahan–Starling–Leland” (BMCSL) theory for the steric interactions among ions.
It is shown that the ionic size differences have a strong bearing on the diffuse part of the electric double layer structure, as well as on the differential capacitance dependence on the surface potential for mixed electrolytes.
American Psychological Association (APA)
López-García, J. J.& Horno, J.& Grosse, C.. 2018. Multiionic and Permittivity-Related Effects on the Diffuse Electric Double Layer Structure at Solid-Electrolyte Solution Interfaces. Advances in Materials Science and Engineering،Vol. 2018, no. 2018, pp.1-11.
https://search.emarefa.net/detail/BIM-1120724
Modern Language Association (MLA)
López-García, J. J.…[et al.]. Multiionic and Permittivity-Related Effects on the Diffuse Electric Double Layer Structure at Solid-Electrolyte Solution Interfaces. Advances in Materials Science and Engineering No. 2018 (2018), pp.1-11.
https://search.emarefa.net/detail/BIM-1120724
American Medical Association (AMA)
López-García, J. J.& Horno, J.& Grosse, C.. Multiionic and Permittivity-Related Effects on the Diffuse Electric Double Layer Structure at Solid-Electrolyte Solution Interfaces. Advances in Materials Science and Engineering. 2018. Vol. 2018, no. 2018, pp.1-11.
https://search.emarefa.net/detail/BIM-1120724
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1120724