Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe
Author
Source
Advances in Condensed Matter Physics
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-37, 37 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-09-18
Country of Publication
Egypt
No. of Pages
37
Main Subjects
Abstract EN
Detailed analytical and numerical analyses are performed for combinations of several complementary sets of measured heat capacities, for ZnSe and ZnTe, from the liquid-helium region up to 600 K.
The isochoric (harmonic) parts of heat capacities, CVh(T), are described within the frame of a properly devised four-oscillator hybrid model.
Additional anharmonicity-related terms are included for comprehensive numerical fittings of the isobaric heat capacities, Cp(T).
The contributions of Debye and non-Debye type due to the low-energy acoustical phonon sections are represented here for the first time by unprecedented, integral-free formulas.
Indications for weak electronic contributions to the cryogenic heat capacities are found for both materials.
A novel analytical framework has been constructed for high-accuracy evaluations of Debye function integrals via a couple of integral-free formulas, consisting of Debye’s conventional low-temperature series expansion in combination with an unprecedented high-temperature series representation for reciprocal values of the Debye function.
The zero-temperature limits of Debye temperatures have been detected from published low-temperature Cp(T) data sets to be significantly lower than previously estimated, namely, 270 (±3) K for ZnSe and 220 (±2) K for ZnTe.
The high-temperature limits of the “true” (harmonic lattice) Debye temperatures are found to be 317 K for ZnSe and 262 K for ZnTe.
American Psychological Association (APA)
Pässler, R.. 2017. Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe. Advances in Condensed Matter Physics،Vol. 2017, no. 2017, pp.1-37.
https://search.emarefa.net/detail/BIM-1121663
Modern Language Association (MLA)
Pässler, R.. Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe. Advances in Condensed Matter Physics No. 2017 (2017), pp.1-37.
https://search.emarefa.net/detail/BIM-1121663
American Medical Association (AMA)
Pässler, R.. Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe. Advances in Condensed Matter Physics. 2017. Vol. 2017, no. 2017, pp.1-37.
https://search.emarefa.net/detail/BIM-1121663
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1121663