Synthesis, Structural Characterization, and Antibacterial Activity of Novel Erbium(III) Complex Containing Antimony
Joint Authors
Zhong, Guo-Qing
Liu, Ting
Yang, Rong-Gui
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-03-20
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The novel 3D edta-linked heterometallic complex [Sb2Er(edta)2(H2O)4]NO3·4H2O (H4edta = ethylenediaminetetraacetic acid) was synthesized and characterized by elemental analyses, single-crystal X-ray diffraction, powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and thermal analysis.
The complex crystallizes in the monoclinic system with space group Pm.
In the complex, each erbium(III) ion is connected with antimony(III) ions bridging by four carboxylic oxygen atoms, and in each [Sb(edta)]− anion, the antimony(III) ion is hexacoordinated by two nitrogen atoms and four oxygen atoms from the edta4− ions, together with a lone electron pair at the equatorial position.
The erbium(III) ion is octacoordinated by four oxygen atoms from four different edta4− ions and four oxygen atoms from the coordinated water molecules.
The carboxylate bridges between antimony and erbium atoms form a planar array, parallel to the (1 0 0) plane.
There is an obvious weak interaction between antimony atom and oxygen atom of the carboxyl group from the adjacent layer.
The degradation of the complex proceeds in several steps and the water molecules and ligands are successively emitted, and the residues of the thermal decomposition are antimonous oxide and erbium(III) oxide.
The complex was evaluated for its antimicrobial activities by agar diffusion method, and it has good activities against the test bacterial organisms.
American Psychological Association (APA)
Liu, Ting& Yang, Rong-Gui& Zhong, Guo-Qing. 2018. Synthesis, Structural Characterization, and Antibacterial Activity of Novel Erbium(III) Complex Containing Antimony. Bioinorganic Chemistry and Applications،Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1123149
Modern Language Association (MLA)
Liu, Ting…[et al.]. Synthesis, Structural Characterization, and Antibacterial Activity of Novel Erbium(III) Complex Containing Antimony. Bioinorganic Chemistry and Applications No. 2018 (2018), pp.1-9.
https://search.emarefa.net/detail/BIM-1123149
American Medical Association (AMA)
Liu, Ting& Yang, Rong-Gui& Zhong, Guo-Qing. Synthesis, Structural Characterization, and Antibacterial Activity of Novel Erbium(III) Complex Containing Antimony. Bioinorganic Chemistry and Applications. 2018. Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1123149
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1123149