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Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine
Joint Authors
Zhong, Guo-Qing
Zang, Qing
Liu, Ting
Wang, Yi-An
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-05-22
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
A Cu(II) complex [Cu(bipy)(H2O)2(SO4)]n (bipy = 2,2′-bipyridine) was synthesized by hydrothermal method and characterized structurally by elemental analyses, single crystal X-ray diffraction, infrared spectra, and thermogravimetry and differential scanning calorimetry.
The Cu(II) was hexacoordinated by two N atoms from bipy, two O atoms from different sulfate radical anions, and two O atoms from two water molecules, forming a slightly distorted octahedral geometry, and bridged by sulfato groups into polymeric chains.
Under the condition of physiological pH, the interaction mechanism between the complex and hsDNA was explored with acridine orange as a fluorescence probe by spectroscopic methods.
The binding modes between the complex and hsDNA were the electrostatic and embedded modes.
American Psychological Association (APA)
Liu, Ting& Wang, Yi-An& Zang, Qing& Zhong, Guo-Qing. 2018. Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine. Bioinorganic Chemistry and Applications،Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1123217
Modern Language Association (MLA)
Liu, Ting…[et al.]. Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine. Bioinorganic Chemistry and Applications No. 2018 (2018), pp.1-10.
https://search.emarefa.net/detail/BIM-1123217
American Medical Association (AMA)
Liu, Ting& Wang, Yi-An& Zang, Qing& Zhong, Guo-Qing. Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine. Bioinorganic Chemistry and Applications. 2018. Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1123217
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1123217