3-Bromopyridine-Heterogenized Phosphotungstic Acid for Efficient Trimerization of Biomass-Derived 5-Hydroxymethylfurfural with 2-Methylfuran to C21 Fuel Precursor
Joint Authors
Yang, Song
Xu, Yufei
Yu, Zhaozhuo
Li, Hu
Source
Advances in Polymer Technology
Issue
Vol. 2020, Issue 2020 (31 Dec. 2020), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2020-08-06
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
The production of long-chain carbon compounds (C9-C21) from biomass derivatives to alternate traditional fossil diesel is sustainable, eco-friendly, and potentially economic for modern industry.
In this work, phosphotungstic acid heterogenized by 3-bromopyridine was achieved using a solvothermal method, which was demonstrated to be efficient for trimerization of biomass-derived 5-hydroxymethylfurfural (HMF) with 2-methylfuran (2-MF) to C21 fuel precursor (57.1% yield) under mild reaction conditions.
The heterogeneous acidic catalyst could be reused for four consecutive cycles without obvious loss of activity, and different characterization techniques (e.g., XRD (X-ray diffraction), TG (thermogravimetric analysis), SEM (scanning electron microscope), FT-IR (Fourier transform infrared spectroscopy), and BET (Brunauer-Emmet-Teller)) were utilized to investigate the performance of the catalyst.
In addition, a plausible reaction pathway was postulated, on the basis of results obtained by NMR (nuclear magnetic resonance) and GC-MS (gas chromatography-mass spectrometer).
This strategy provides a facile and efficient approach to prepare a recyclable acidic catalyst for the production of diesel fuel precursor from biomass via controllable polymerization.
American Psychological Association (APA)
Xu, Yufei& Yu, Zhaozhuo& Li, Hu& Yang, Song. 2020. 3-Bromopyridine-Heterogenized Phosphotungstic Acid for Efficient Trimerization of Biomass-Derived 5-Hydroxymethylfurfural with 2-Methylfuran to C21 Fuel Precursor. Advances in Polymer Technology،Vol. 2020, no. 2020, pp.1-12.
https://search.emarefa.net/detail/BIM-1130305
Modern Language Association (MLA)
Xu, Yufei…[et al.]. 3-Bromopyridine-Heterogenized Phosphotungstic Acid for Efficient Trimerization of Biomass-Derived 5-Hydroxymethylfurfural with 2-Methylfuran to C21 Fuel Precursor. Advances in Polymer Technology No. 2020 (2020), pp.1-12.
https://search.emarefa.net/detail/BIM-1130305
American Medical Association (AMA)
Xu, Yufei& Yu, Zhaozhuo& Li, Hu& Yang, Song. 3-Bromopyridine-Heterogenized Phosphotungstic Acid for Efficient Trimerization of Biomass-Derived 5-Hydroxymethylfurfural with 2-Methylfuran to C21 Fuel Precursor. Advances in Polymer Technology. 2020. Vol. 2020, no. 2020, pp.1-12.
https://search.emarefa.net/detail/BIM-1130305
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1130305