Peroxymonosulfate Activation on a Hybrid Material of Conjugated PVC and TiO2 Nanotubes for Enhancing Degradation of Rhodamine B under Visible Light

Abstract EN

Visible-light-driven photocatalysis is a robust technology for amending the negative effect of pollutants on the environment with a minimum energy use.

Herein, we describe a simple approach to producing such a photocatalyst by coupling conjugated polyvinyl chloride (cPVC) with the TiO2 nanotube (TNT) thermolysis method.

By activating peroxymonosulfate (PMS) to make a cPVC/TNT/PMS system using visible light as the source, we obtain a significant enhancement in the photocatalytic performance.

We show that PMS use at a concentration of 3 mM can fully degrade rhodamine B (RhB) solution at a remarkably high concentration (200 mg L-1) just in 120 min under visible light.

The cPVC/TNT/PMS system also shows excellent stability in recycling tests for at least five times.

Further, by confining the active species in photocatalytic reactions, we report a thorough understanding of the extent of involvement from those radicals.

Our work presents a robust approach to make a high-performance, visible-light-driven photocatalyst, which can be potentially used in practice.