Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Cadmium from Aqueous Solution by Modified Biomass Ash
Joint Authors
Xu, Lei
Zheng, Xuebo
Cui, Hongbiao
Zhu, Zhenqiu
Liang, Jiani
Zhou, Jing
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-02-28
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
Natural biomass ash of agricultural residuals was collected from a power plant and modified with hexagonal mesoporous silica and functionalized with 3-aminopropyltriethoxysilane.
The physicochemical and morphological properties of the biomass ash were analyzed by ICP-OES, SEM, TEM-EDS, FTIR, and BET analysis.
The adsorption behavior of the modified product for Cd2+ in aqueous solution was studied as a function of pH, initial metal concentration, equilibrium time, and temperature.
Results showed that the specific surface area of the modified product was 9 times that of the natural biomass ash.
The modified biomass ash exhibited high affinity for Cd2+ and its adsorption capacity increased sharply with increasing pH from 4.0 to 6.0.
The maximum adsorption capacity was 23.95 mg/g in a pH 5 solution with an initial metal concentration of 50 mg/L and a contact time of 90 min.
The adsorption of Cd2+ onto the modified biomass ash was well fitted to the Langmuir model and it followed pseudo-second-order kinetics.
Thermodynamic analysis results showed that the adsorption of Cd2+ was spontaneous and endothermic in nature.
The results suggest that the modified biomass ash is promising for use as an inexpensive and effective adsorbent for Cd2+ removal from aqueous solution.
American Psychological Association (APA)
Xu, Lei& Zheng, Xuebo& Cui, Hongbiao& Zhu, Zhenqiu& Liang, Jiani& Zhou, Jing. 2017. Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Cadmium from Aqueous Solution by Modified Biomass Ash. Bioinorganic Chemistry and Applications،Vol. 2017, no. 2017, pp.1-9.
https://search.emarefa.net/detail/BIM-1131128
Modern Language Association (MLA)
Xu, Lei…[et al.]. Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Cadmium from Aqueous Solution by Modified Biomass Ash. Bioinorganic Chemistry and Applications No. 2017 (2017), pp.1-9.
https://search.emarefa.net/detail/BIM-1131128
American Medical Association (AMA)
Xu, Lei& Zheng, Xuebo& Cui, Hongbiao& Zhu, Zhenqiu& Liang, Jiani& Zhou, Jing. Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Cadmium from Aqueous Solution by Modified Biomass Ash. Bioinorganic Chemistry and Applications. 2017. Vol. 2017, no. 2017, pp.1-9.
https://search.emarefa.net/detail/BIM-1131128
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1131128