Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes
Joint Authors
Kuo, Yueh-Hsiung
Chern, Ching-Yuh
Tseng, Ching-Chun
Hsiao, Rong-Hong
Wong, Fung Fuh
Source
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-08-18
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
This work reports an efficient method for the oxidation reaction of aliphatic, aromatic allylic, and benzylic alcohols into aldehydes catalyzed by the cyclopentadienyl ruthenium(II) complex (RuCpCl(PPh3)2) with bubbled O2.
Through further optimizing controlled studies, the tendency order of oxidation reactivity was determined as follows: benzylic alcohols > aromatic allylic alcohols >> aliphatic alcohols.
In addition, this method has several advantages, including a small amount of catalyst (0.5 mol%) and selective application of high discrimination activity of aliphatic, aromatic allylic, and benzylic alcohols.
American Psychological Association (APA)
Chern, Ching-Yuh& Tseng, Ching-Chun& Hsiao, Rong-Hong& Wong, Fung Fuh& Kuo, Yueh-Hsiung. 2019. Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes. Heteroatom Chemistry،Vol. 2019, no. 2019, pp.1-8.
https://search.emarefa.net/detail/BIM-1155656
Modern Language Association (MLA)
Chern, Ching-Yuh…[et al.]. Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes. Heteroatom Chemistry No. 2019 (2019), pp.1-8.
https://search.emarefa.net/detail/BIM-1155656
American Medical Association (AMA)
Chern, Ching-Yuh& Tseng, Ching-Chun& Hsiao, Rong-Hong& Wong, Fung Fuh& Kuo, Yueh-Hsiung. Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes. Heteroatom Chemistry. 2019. Vol. 2019, no. 2019, pp.1-8.
https://search.emarefa.net/detail/BIM-1155656
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1155656