Simultaneous Determination of Four Aldehydes in Gas Phase of Mainstream Smoke by Headspace Gas Chromatography-Mass Spectrometry

Joint Authors

Zhang, Xiaotao
Wang, Ruoning
Zhang, Li
Wei, Jianke
Ruan, Yibin
Wang, Weiwei
Ji, Houwei
Liu, Jian

Source

International Journal of Analytical Chemistry

Issue

Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-6, 6 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2019-02-03

Country of Publication

Egypt

No. of Pages

6

Main Subjects

Chemistry
Science

Abstract EN

A method for simultaneous determination of acetaldehyde, propionaldehyde, acrolein, and crotonaldehyde in gas phase of cigarette mainstream smoke by headspace gas chromatography-mass spectrometry was developed and validated.

Gas phase components of mainstream cigarette smoke were extracted with methanol, and then the samples were separated on a DB 624 (60 m, 0.32 mm x 1.8 mm) column, analyzed with headspace gas chromatography-mass spectrometry, and quantified by isotope internal standard.

The linearities of acetaldehyde, propionaldehyde, acrolein, and crotonaldehyde were good (R 2>0.992).

The recoveries of acetaldehyde, propionaldehyde, acrolein, and crotonaldehyde were between 78.5% and 115%.

The relative standard deviations were less than 10%.

The limits of detection and limits of quantitation were 0.014 μg/cigarette ~0.12 μg/cigarette and 0.045 μg/cigarette ~0.38 μg/cigarette, respectively.

The method had advantage of high sensitivity, it did not require derivatization of 2,4-dinitrophenylhydrazine and avoided a large number of adverse reactions during the process of derivation to improve the accuracy of result, and it was suitable for quantitative analysis of four aldehydes in gas phase of cigarette mainstream smoke.

American Psychological Association (APA)

Zhang, Xiaotao& Wang, Ruoning& Zhang, Li& Wei, Jianke& Ruan, Yibin& Wang, Weiwei…[et al.]. 2019. Simultaneous Determination of Four Aldehydes in Gas Phase of Mainstream Smoke by Headspace Gas Chromatography-Mass Spectrometry. International Journal of Analytical Chemistry،Vol. 2019, no. 2019, pp.1-6.
https://search.emarefa.net/detail/BIM-1155848

Modern Language Association (MLA)

Zhang, Xiaotao…[et al.]. Simultaneous Determination of Four Aldehydes in Gas Phase of Mainstream Smoke by Headspace Gas Chromatography-Mass Spectrometry. International Journal of Analytical Chemistry No. 2019 (2019), pp.1-6.
https://search.emarefa.net/detail/BIM-1155848

American Medical Association (AMA)

Zhang, Xiaotao& Wang, Ruoning& Zhang, Li& Wei, Jianke& Ruan, Yibin& Wang, Weiwei…[et al.]. Simultaneous Determination of Four Aldehydes in Gas Phase of Mainstream Smoke by Headspace Gas Chromatography-Mass Spectrometry. International Journal of Analytical Chemistry. 2019. Vol. 2019, no. 2019, pp.1-6.
https://search.emarefa.net/detail/BIM-1155848

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-1155848