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The Adsorption of Pb, Zn, Cu, Ni, and Cd by Modified Ligand in a Single Component Aqueous Solution: Equilibrium, Kinetic, Thermodynamic, and Desorption Studies
Joint Authors
Igberase, E.
Osifo, P.
Ofomaja, A.
Source
International Journal of Analytical Chemistry
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-15, 15 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-05-18
Country of Publication
Egypt
No. of Pages
15
Main Subjects
Abstract EN
In this investigation, an amino functionalized adsorbent was developed by grafting 4-aminobenzoic acid onto the backbone of cross-linked chitosan beads.
The 3 sets of beads including chitosan (CX), glutaraldehyde cross-linked chitosan (CCX), and 4-aminobenzoic acid grafted cross-linked chitosan (FGCX) were characterized by FTIR, XRD, SEM, and TGA.
The water content and amine concentration of FGCX were determined.
The effect of adsorption parameters was studied and the optimum was used for further studies.
Equilibrium data was obtained from the adsorption experiment carried out at different initial concentration; the data were applied in isotherm, thermodynamics, and kinetic studies.
The Langmuir and Dubinin-Kaganer-Radushkevich (DKR) models were successful in describing the isotherm data for the considered metal ions while the Freundlich and Temkin model fit some of the considered metal ions.
Pseudo-second-order and intraparticle model described the kinetic data quite well.
Thermodynamic parameters such as Gibb’s free energy change (ΔGo), enthalpy change (ΔHo), and entropy change (ΔSo) were calculated and the results showed that the adsorption of Pb, Cu, Ni, Zn, and Cd ions onto FGCX is spontaneous and endothermic in nature.
Regeneration of the spent adsorbent was efficient for the considered metal ions.
American Psychological Association (APA)
Igberase, E.& Osifo, P.& Ofomaja, A.. 2017. The Adsorption of Pb, Zn, Cu, Ni, and Cd by Modified Ligand in a Single Component Aqueous Solution: Equilibrium, Kinetic, Thermodynamic, and Desorption Studies. International Journal of Analytical Chemistry،Vol. 2017, no. 2017, pp.1-15.
https://search.emarefa.net/detail/BIM-1157588
Modern Language Association (MLA)
Igberase, E.…[et al.]. The Adsorption of Pb, Zn, Cu, Ni, and Cd by Modified Ligand in a Single Component Aqueous Solution: Equilibrium, Kinetic, Thermodynamic, and Desorption Studies. International Journal of Analytical Chemistry No. 2017 (2017), pp.1-15.
https://search.emarefa.net/detail/BIM-1157588
American Medical Association (AMA)
Igberase, E.& Osifo, P.& Ofomaja, A.. The Adsorption of Pb, Zn, Cu, Ni, and Cd by Modified Ligand in a Single Component Aqueous Solution: Equilibrium, Kinetic, Thermodynamic, and Desorption Studies. International Journal of Analytical Chemistry. 2017. Vol. 2017, no. 2017, pp.1-15.
https://search.emarefa.net/detail/BIM-1157588
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1157588