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Inexpensive Bismuth-Film Electrode Supported on Pencil-Lead Graphite for Determination of Pb(II) and Cd(II) Ions by Anodic Stripping Voltammetry
Joint Authors
Bedin, Karen C.
Mitsuyasu, Edson Y.
Ronix, Amanda
Cazetta, André L.
Pezoti, Osvaldo
Almeida, Vitor C.
Source
International Journal of Analytical Chemistry
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-10-08
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The present work reports the development and application of bismuth-film electrode (BiFE), obtained by in situ method on the pencil-lead graphite surface, for simultaneous Cd(II) and Pb(II) determination at trace levels, as alternative to replace the mercury-film electrodes.
Experimental factors, deposition time (td), deposition potential (Ed), and Bi(III) concentration (CBi), were investigated by applying a 23 factorial design using 0.10 mol/L acetate buffer solution (pH 4.5) as supporting electrolyte.
The analysis conditions of the differential pulse technique were td = 250 s, Ed = -1.40 V, and CBi = 250 mg L−1.
The validation of the method employing BiFE was accomplished by determination of merit figures.
The detection limits were of 11.0 μg L−1 for Cd(II) and 11.5 μg L−1 for Pb(II), confirming that proposed method is attractive and suitable for heavy metals determination.
Additionally, the BiFE developed was successfully applied for the Cd(II) and Pb(II) determination in wastewater sample of battery industry.
American Psychological Association (APA)
Bedin, Karen C.& Mitsuyasu, Edson Y.& Ronix, Amanda& Cazetta, André L.& Pezoti, Osvaldo& Almeida, Vitor C.. 2018. Inexpensive Bismuth-Film Electrode Supported on Pencil-Lead Graphite for Determination of Pb(II) and Cd(II) Ions by Anodic Stripping Voltammetry. International Journal of Analytical Chemistry،Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1166290
Modern Language Association (MLA)
Bedin, Karen C.…[et al.]. Inexpensive Bismuth-Film Electrode Supported on Pencil-Lead Graphite for Determination of Pb(II) and Cd(II) Ions by Anodic Stripping Voltammetry. International Journal of Analytical Chemistry No. 2018 (2018), pp.1-9.
https://search.emarefa.net/detail/BIM-1166290
American Medical Association (AMA)
Bedin, Karen C.& Mitsuyasu, Edson Y.& Ronix, Amanda& Cazetta, André L.& Pezoti, Osvaldo& Almeida, Vitor C.. Inexpensive Bismuth-Film Electrode Supported on Pencil-Lead Graphite for Determination of Pb(II) and Cd(II) Ions by Anodic Stripping Voltammetry. International Journal of Analytical Chemistry. 2018. Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1166290
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1166290