Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography
Author
Source
International Journal of Polymer Science
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-05-21
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
In this study, the effects of probe quantities on retention volume and the physical and thermodynamic results of polymer-probe systems were investigated.
For this purpose, by using inverse gas chromatographic method.
Alcohols and alkanes with different chemical and physical properties were injected as probes on homopolymer (2-cyclohexylidene-1,3-dioxolane-4-yl-methyl methacrylate) (CHMMA).
Probe quantities of 0.3, 0.6, and 0.9 μl were selected, and an injection was made at every 10°C between 40 and 150°C.
In addition, 3 μl volume probes were tried but reproducible results were not obtained in these volumes and the detector was observed to be out of order after several injections.
It has been observed that the specific retention volume of alcohols and alkanes partially increased by increasing the injection amount.
A linear relationship was observed between probe quantities and specific retention volume.
This linear relationship is apparent from the specific retention volume values, where the probes are independent of the physical and chemical structures.
It was observed that the results obtained in all three injections were close to each other and within acceptable limits.
The glass transition temperature of the polymer was determined to be a Tg of 60°C.
The thermodynamic data calculated for the injection of different amounts of probes were close to each other.
American Psychological Association (APA)
Karagöz, Mustafa Hamdi. 2019. Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography. International Journal of Polymer Science،Vol. 2019, no. 2019, pp.1-11.
https://search.emarefa.net/detail/BIM-1168077
Modern Language Association (MLA)
Karagöz, Mustafa Hamdi. Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography. International Journal of Polymer Science No. 2019 (2019), pp.1-11.
https://search.emarefa.net/detail/BIM-1168077
American Medical Association (AMA)
Karagöz, Mustafa Hamdi. Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography. International Journal of Polymer Science. 2019. Vol. 2019, no. 2019, pp.1-11.
https://search.emarefa.net/detail/BIM-1168077
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1168077