Physicochemical and Luminescent Properties of Copolymers Composed of Three Monomers: Polythiophenes Based on 3-Hexylthiophene and 3,4-Ethylenedioxythiophene
Joint Authors
Güizado-Rodríguez, Marisol
Ramos-Ortiz, Gabriel
Rodríguez, Mario
Maldonado, José-Luis
Barba, Victor
Ramírez-Gómez, Marco Antonio
Guzmán-Rabadán, Karla Karina
González-Juárez, Edgar
Alba-Rosales, Jorge Enrique
Panzo-Medrano, Huehueteotl
Basurto, Miguel
Source
International Journal of Polymer Science
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-05-11
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
The chemical synthesis and physicochemical and luminescent characterizations of polymers based on 3-HT, EDOT, and 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl) bisthiophene (fluorene) or (E)-2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethyl 2-(thiophen-3-yl)acetate (TDR1) are reported.
The fluorene unit was bound to the conjugate backbone, while the Disperse Red 1 (DR1) chromophore was present as a pendant group.
Characterizations by 1H NMR, FT-IR, DSC-TGA, GPC, UV-vis, cyclic voltammetry, fluorescence quantum yield, excited state lifetime, and two-photon absorption cross-section were carried out.
These polymers combined the physicochemical properties of EDOT and 3-HT, such as high electron density, high charge mobility, low oxidation potential, and good processability.
The optical properties of these copolymers were highly dependent on the presence of EDOT, the molecular weight, and the regioregularity rather than the presence of the third component (fluorene or TDR1).
The good nonlinear absorption and luminescent properties exhibited by these copolymers were exploited to fabricate nanoparticles used as fluorescent tags for the imaging of microstructures.
American Psychological Association (APA)
Ramírez-Gómez, Marco Antonio& Guzmán-Rabadán, Karla Karina& González-Juárez, Edgar& Güizado-Rodríguez, Marisol& Ramos-Ortiz, Gabriel& Alba-Rosales, Jorge Enrique…[et al.]. 2017. Physicochemical and Luminescent Properties of Copolymers Composed of Three Monomers: Polythiophenes Based on 3-Hexylthiophene and 3,4-Ethylenedioxythiophene. International Journal of Polymer Science،Vol. 2017, no. 2017, pp.1-11.
https://search.emarefa.net/detail/BIM-1168835
Modern Language Association (MLA)
Ramírez-Gómez, Marco Antonio…[et al.]. Physicochemical and Luminescent Properties of Copolymers Composed of Three Monomers: Polythiophenes Based on 3-Hexylthiophene and 3,4-Ethylenedioxythiophene. International Journal of Polymer Science No. 2017 (2017), pp.1-11.
https://search.emarefa.net/detail/BIM-1168835
American Medical Association (AMA)
Ramírez-Gómez, Marco Antonio& Guzmán-Rabadán, Karla Karina& González-Juárez, Edgar& Güizado-Rodríguez, Marisol& Ramos-Ortiz, Gabriel& Alba-Rosales, Jorge Enrique…[et al.]. Physicochemical and Luminescent Properties of Copolymers Composed of Three Monomers: Polythiophenes Based on 3-Hexylthiophene and 3,4-Ethylenedioxythiophene. International Journal of Polymer Science. 2017. Vol. 2017, no. 2017, pp.1-11.
https://search.emarefa.net/detail/BIM-1168835
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1168835