Electrical, Thermal, and Morphological Properties of Poly(ethylene terephthalate)-Graphite Nanoplatelets Nanocomposites
Joint Authors
Alshammari, Basheer A.
Wilkinson, Arthur N.
Almutairi, Ghzzai
Source
International Journal of Polymer Science
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-10-23
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
Graphite nanoplatelets (GNP) were incorporated with poly(ethylene terephthalate) (PET) matrix by melt-compounding technique using minilab compounder to produce PET-GNP nanocomposites, and then the extruded nanocomposites were compressed using compression molding to obtain films of 1 mm thickness.
Percolation threshold value was determined using percolation theory.
The electrical conductivity, morphology, and thermal behaviors of these nanocomposites were investigated at different contents of GNP, that is, below, around, and above its percolation threshold value.
The results demonstrated that the addition of GNP at loading >5 wt.% made electrically conductive nanocomposites.
An excellent electrical conductivity of ~1 S/m was obtained at 15 wt.% of GNP loading.
The nanocomposites showed a typical insulator-conductor transition with a percolation threshold value of 5.7 wt.% of GNP.
In addition, increasing screw speed enhanced the conductivity of the nanocomposites above its threshold value by ~2.5 orders of magnitude; this behavior is attributed to improved dispersion of these nanoparticles into the PET matrix.
Microscopies results exhibited no indication of aggregations at 2 wt.% of GNP; however, some rolling up at 6 wt.% of GNP contents was observed, indicating that a conductive network has been formed, whereas more agglomeration and rolling up could be seen as the GNP content is increased in the PET matrix.
These agglomerations reduced their aspect ratio and then reduced their reinforcement efficiency.
NP loading (>2 wt.%) increased degree of crystallinity and improved thermal stability of matrix slightly, suggesting that 2 wt.% of GNP is more than enough to nucleate the matrix.
American Psychological Association (APA)
Alshammari, Basheer A.& Wilkinson, Arthur N.& Almutairi, Ghzzai. 2017. Electrical, Thermal, and Morphological Properties of Poly(ethylene terephthalate)-Graphite Nanoplatelets Nanocomposites. International Journal of Polymer Science،Vol. 2017, no. 2017, pp.1-9.
https://search.emarefa.net/detail/BIM-1169130
Modern Language Association (MLA)
Alshammari, Basheer A.…[et al.]. Electrical, Thermal, and Morphological Properties of Poly(ethylene terephthalate)-Graphite Nanoplatelets Nanocomposites. International Journal of Polymer Science No. 2017 (2017), pp.1-9.
https://search.emarefa.net/detail/BIM-1169130
American Medical Association (AMA)
Alshammari, Basheer A.& Wilkinson, Arthur N.& Almutairi, Ghzzai. Electrical, Thermal, and Morphological Properties of Poly(ethylene terephthalate)-Graphite Nanoplatelets Nanocomposites. International Journal of Polymer Science. 2017. Vol. 2017, no. 2017, pp.1-9.
https://search.emarefa.net/detail/BIM-1169130
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1169130