Use of TBzTD as Noncarcinogenic Accelerator for ENRSiO2 Nanocomposites: Cured Characteristics, Mechanical Properties, Thermal Behaviors, and Oil Resistance
Joint Authors
Raksaksri, Laksamon
Chuayjuljit, Saowaroj
Chaiwutthinan, Phasawat
Boonmahitthisud, Anyaporn
Source
International Journal of Polymer Science
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-07-31
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
This study reported the use of tetrabenzylthiuram disulphide (TBzTD) as a noncarcinogenic accelerator in a traditional sulfur curing system of epoxidized natural rubber (ENR)/nanosilica (nSiO2) composites.
ENR used in this work was synthesized via in situ epoxidation of natural rubber (NR) in the presence of performic acid generated from the reaction of formic acid and hydrogen peroxide at 50°C for 8 h to acquire the epoxide content of about 40 mol%.
Accordingly, the resulting ENR was referred to as ENR 40.
The curing characteristics, mechanical properties, thermal behaviors, dynamic mechanical properties, and oil resistance of ENR 40/nSiO2 nanocomposites filled with three loadings of nSiO2 (1, 2, and 3 parts per hundred parts of rubber) were investigated and compared with NR and neat ENR 40.
The results revealed that the scorch and cure times of ENR 40/nSiO2 nanocomposites were slightly longer than those of NR but slightly shorter than those of ENR 40.
The tensile properties and tear strength for both before and after aging of all ENR 40/nSiO2 nanocomposites were higher than those of ENR 40, while the glass transition temperature, storage modulus at −65°C, thermal stability, and oil resistance of ENR 40/nSiO2 nanocomposites were higher than those of NR and ENR 40.
American Psychological Association (APA)
Raksaksri, Laksamon& Chuayjuljit, Saowaroj& Chaiwutthinan, Phasawat& Boonmahitthisud, Anyaporn. 2017. Use of TBzTD as Noncarcinogenic Accelerator for ENRSiO2 Nanocomposites: Cured Characteristics, Mechanical Properties, Thermal Behaviors, and Oil Resistance. International Journal of Polymer Science،Vol. 2017, no. 2017, pp.1-11.
https://search.emarefa.net/detail/BIM-1169318
Modern Language Association (MLA)
Raksaksri, Laksamon…[et al.]. Use of TBzTD as Noncarcinogenic Accelerator for ENRSiO2 Nanocomposites: Cured Characteristics, Mechanical Properties, Thermal Behaviors, and Oil Resistance. International Journal of Polymer Science No. 2017 (2017), pp.1-11.
https://search.emarefa.net/detail/BIM-1169318
American Medical Association (AMA)
Raksaksri, Laksamon& Chuayjuljit, Saowaroj& Chaiwutthinan, Phasawat& Boonmahitthisud, Anyaporn. Use of TBzTD as Noncarcinogenic Accelerator for ENRSiO2 Nanocomposites: Cured Characteristics, Mechanical Properties, Thermal Behaviors, and Oil Resistance. International Journal of Polymer Science. 2017. Vol. 2017, no. 2017, pp.1-11.
https://search.emarefa.net/detail/BIM-1169318
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1169318