Densities, Apparent Molar Volume, Expansivities, Hepler’s Constant, and Isobaric Thermal Expansion Coefficients of the Binary Mixtures of Piperazine with Water, Methanol, and Acetone at T = 293.15 to 328.15 K
Joint Authors
Omar, Qazi Mohammed
Jaubert, Jean-Noël
Awan, Javeed A.
Source
International Journal of Chemical Engineering
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-11-14
Country of Publication
Egypt
No. of Pages
10
Abstract EN
The properties of 3 binary mixtures containing piperazine were investigated in this work.
In a first step, the densities for the two binary mixtures (piperazine + methanol) and (piperazine + acetone) were measured in the temperature range of 293.15 to 328.15 K and 293.15 to 323.15 K, respectively, at atmospheric pressure by using a Rudolph research analytical density meter (DDM 2911).
The concentration of piperazine in the (piperazine + methanol) mixture was varied from 0.6978 to 14.007 mol/kg, and the concentration of piperazine in the (piperazine + acetone) mixture was varied from 0.3478 to 1.8834 mol/kg.
On the other hand, the density data for the (piperazine + water) mixture were taken from the literature in the temperature range of 298.15 to 328.15 K.
In a second step, for the 3 investigated systems, the apparent molar volume (Vϕ) and the limiting apparent molar volume (Vϕ0) at infinite dilution were calculated using the Redlich–Mayer equation.
The limiting apparent molar volumes (Vϕ0) were used to study the influence of the solute-solvent and solute-solute interactions.
The temperature dependency of the apparent molar volumes was used to estimate the apparent molar expansibility, Hepler’s constant ∂2Vϕ0/∂T2P, and isobaric thermal expansion coefficients αP.
American Psychological Association (APA)
Omar, Qazi Mohammed& Jaubert, Jean-Noël& Awan, Javeed A.. 2018. Densities, Apparent Molar Volume, Expansivities, Hepler’s Constant, and Isobaric Thermal Expansion Coefficients of the Binary Mixtures of Piperazine with Water, Methanol, and Acetone at T = 293.15 to 328.15 K. International Journal of Chemical Engineering،Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1170235
Modern Language Association (MLA)
Omar, Qazi Mohammed…[et al.]. Densities, Apparent Molar Volume, Expansivities, Hepler’s Constant, and Isobaric Thermal Expansion Coefficients of the Binary Mixtures of Piperazine with Water, Methanol, and Acetone at T = 293.15 to 328.15 K. International Journal of Chemical Engineering No. 2018 (2018), pp.1-10.
https://search.emarefa.net/detail/BIM-1170235
American Medical Association (AMA)
Omar, Qazi Mohammed& Jaubert, Jean-Noël& Awan, Javeed A.. Densities, Apparent Molar Volume, Expansivities, Hepler’s Constant, and Isobaric Thermal Expansion Coefficients of the Binary Mixtures of Piperazine with Water, Methanol, and Acetone at T = 293.15 to 328.15 K. International Journal of Chemical Engineering. 2018. Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1170235
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1170235