High-Sensitivity Determination of K, Ca, Na, and Mg in Salt Mines Samples by Atomic Emission Spectrometry with a Miniaturized Liquid Cathode Glow Discharge
Joint Authors
Yu, Jie
Zhang, Zhichao
Lu, Quanfang
Sun, Duixiong
Zhu, Shuwen
Zhang, Xiaomin
Wang, Xing
Yang, Wu
Source
Journal of Analytical Methods in Chemistry
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-11-07
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
An atomic emission spectrometer (AES) based on a novel atmospheric pressure liquid cathode glow discharge (LCGD) as one of the most promising miniaturized excitation sources has been developed, in which the glow discharge is produced between a needle-like Pt anode and the electrolyte (as cathode) overflowing from a quartz capillary.
Lower energy consumption (<50 W) and higher excitation efficiency can be realized by point discharge of the needle-like Pt.
The miniaturized LCGD seems particularly well suited to rapid and high-sensitivity determination of K, Ca, Na, and Mg in salt mines samples.
The optimized analytical conditions of LCGD-AES were pH = 1 with HNO3 as electrolyte, 650 V discharge voltage, and 3 mL min−1 solution flow rate.
The limits of detections (LODs) of K, Ca, Na, and Mg were 0.390, 0.054, 0.048, and 0.032 mg L−1, respectively.
Measurement results of the LCGD-AES are in good agreement with the comparison value obtained by inductively coupled plasma (ICP) and ion chromatography (IC).
All results suggested that the developed portable analytical instrument can be used for on-site and real-time monitoring of metal elements in field with further improvement.
American Psychological Association (APA)
Yu, Jie& Zhang, Zhichao& Lu, Quanfang& Sun, Duixiong& Zhu, Shuwen& Zhang, Xiaomin…[et al.]. 2017. High-Sensitivity Determination of K, Ca, Na, and Mg in Salt Mines Samples by Atomic Emission Spectrometry with a Miniaturized Liquid Cathode Glow Discharge. Journal of Analytical Methods in Chemistry،Vol. 2017, no. 2017, pp.1-10.
https://search.emarefa.net/detail/BIM-1170280
Modern Language Association (MLA)
Yu, Jie…[et al.]. High-Sensitivity Determination of K, Ca, Na, and Mg in Salt Mines Samples by Atomic Emission Spectrometry with a Miniaturized Liquid Cathode Glow Discharge. Journal of Analytical Methods in Chemistry No. 2017 (2017), pp.1-10.
https://search.emarefa.net/detail/BIM-1170280
American Medical Association (AMA)
Yu, Jie& Zhang, Zhichao& Lu, Quanfang& Sun, Duixiong& Zhu, Shuwen& Zhang, Xiaomin…[et al.]. High-Sensitivity Determination of K, Ca, Na, and Mg in Salt Mines Samples by Atomic Emission Spectrometry with a Miniaturized Liquid Cathode Glow Discharge. Journal of Analytical Methods in Chemistry. 2017. Vol. 2017, no. 2017, pp.1-10.
https://search.emarefa.net/detail/BIM-1170280
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1170280