Rapid Determination of Six Low Molecular Carbonyl Compounds in Tobacco Smoke by the APCI-MSMS Coupled to Data Mining
Joint Authors
Zhao, Wuduo
Zhang, Shusheng
Zhang, Qidong
Lu, Binbin
Sun, Shihao
Zhang, Jianxun
Source
Journal of Analytical Methods in Chemistry
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-04-20
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
A simple method was established for the rapid determination of low molecular carbonyl compounds by the combination of atmospheric pressure chemical ionization tandem mass spectrometry (APCI-MS/MS) and data mining.
The ionization was carried out in positive mode, and six low molecular carbonyl compounds of acrolein, acetone, propionaldehyde, crotonaldehyde, butanone, and butyraldehyde were analyzed by both full scan mode and daughter scan mode.
To overcome the quantitative difficulties from isomer of acetone/propionaldehyde and butanone/butyraldehyde, the quantitation procedure was performed with the characteristic ion of [CH3O]+ under CID energy of 5 and 15 eV.
Subsequently, the established method was successfully applied to analysis of six low molecular carbonyl compounds in tobacco smoke with analytical period less than four minutes.
The contents of acrolein, acetone, propionaldehyde, crotonaldehyde, butanone, and butyraldehyde for a cigarette were about 63±5.8, 325±82, 55±9.7, 11±1.4, 67±5.9, and 12±1.8 μg/cig, respectively.
The experimental results indicated that the established method had the potential application in rapid determination of low molecular carbonyl compounds.
American Psychological Association (APA)
Zhao, Wuduo& Zhang, Qidong& Lu, Binbin& Sun, Shihao& Zhang, Shusheng& Zhang, Jianxun. 2017. Rapid Determination of Six Low Molecular Carbonyl Compounds in Tobacco Smoke by the APCI-MSMS Coupled to Data Mining. Journal of Analytical Methods in Chemistry،Vol. 2017, no. 2017, pp.1-7.
https://search.emarefa.net/detail/BIM-1170326
Modern Language Association (MLA)
Zhao, Wuduo…[et al.]. Rapid Determination of Six Low Molecular Carbonyl Compounds in Tobacco Smoke by the APCI-MSMS Coupled to Data Mining. Journal of Analytical Methods in Chemistry No. 2017 (2017), pp.1-7.
https://search.emarefa.net/detail/BIM-1170326
American Medical Association (AMA)
Zhao, Wuduo& Zhang, Qidong& Lu, Binbin& Sun, Shihao& Zhang, Shusheng& Zhang, Jianxun. Rapid Determination of Six Low Molecular Carbonyl Compounds in Tobacco Smoke by the APCI-MSMS Coupled to Data Mining. Journal of Analytical Methods in Chemistry. 2017. Vol. 2017, no. 2017, pp.1-7.
https://search.emarefa.net/detail/BIM-1170326
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1170326