Structure and Electrochemical Properties of Li4Ti5O12 Prepared via Low-Temperature Precipitation

Abstract EN

This work aimed to prepare the spinel phase Li4Ti5O12 by a combination of the low-temperature precipitation technique and assisted calcination step.

X-ray diffraction (XRD) revealed that the intermediated phase was Li2TiO3, and the spinel phase could be evidently formed at 700°C for 12 to 20 hours.

The morphology of spinel powder, determined by SEM and TEM, exhibited a good distribution at the submicrometric scale that promoted a fast kinetic of Li migration and an excellent performance at the high-rate cycling test.

The stable performances were achieved in the charge-discharge test at different current densities: 80 mA/g (165 mAh/g), 320 mA (160 mAh/g), and 1600 mA (145 mAh/g) upon 100 cycles.

Moreover, we observe a capacity retention of 48% (corresponding 80 mA/g) at a high rate of 5000 mAh/g.

The cyclic voltammetry measurement displayed a reversible system and revealed the lithium diffusion coefficient of 1.15 × 10−11 cm2/s.