Synthesis, Single Crystal Growth, and Properties of Cobalt Deficient Double Perovskite EuBaCo2−xO6−δ (x = 0–0.1)
Joint Authors
Zuev, Andrey Yu
Tsvetkov, Dmitry S.
Telegin, S. V.
Naumov, S. V.
Patrakov, E. I.
Source
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-07-05
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Abstract EN
The cobalt deficient double perovskites EuBaCo2−xO6−δ with x=0–0.1 were obtained both as powders and as single crystal.
Formation of cobalt vacancies in their crystal lattice was shown to be accompanied by the formation of oxygen ones.
Chemical lattice strain caused by this cooperative disordering of cobalt and oxygen sublattices was found to be isotropic contrary to that caused by the formation of oxygen vacancies only.
Cobalt deficiency was also shown to lead to lowering overall conductivity and Seebeck coefficient of EuBaCo2−xO6−δ double perovskites as a result of simultaneous decrease of charge carriers’ concentration and their mobility as well as number of sites available for electrons and holes transfer.
Strong anisotropy of the overall conductivity of the single crystal double perovskites EuBaCo2−xO6−δ was found and explained on the basis of preferential location of oxygen vacancies in the rare-earth-oxygen- (REO-) planes.
American Psychological Association (APA)
Telegin, S. V.& Zuev, Andrey Yu& Naumov, S. V.& Patrakov, E. I.& Tsvetkov, Dmitry S.. 2017. Synthesis, Single Crystal Growth, and Properties of Cobalt Deficient Double Perovskite EuBaCo2−xO6−δ (x = 0–0.1). Journal of Chemistry،Vol. 2017, no. 2017, pp.1-5.
https://search.emarefa.net/detail/BIM-1171637
Modern Language Association (MLA)
Telegin, S. V.…[et al.]. Synthesis, Single Crystal Growth, and Properties of Cobalt Deficient Double Perovskite EuBaCo2−xO6−δ (x = 0–0.1). Journal of Chemistry No. 2017 (2017), pp.1-5.
https://search.emarefa.net/detail/BIM-1171637
American Medical Association (AMA)
Telegin, S. V.& Zuev, Andrey Yu& Naumov, S. V.& Patrakov, E. I.& Tsvetkov, Dmitry S.. Synthesis, Single Crystal Growth, and Properties of Cobalt Deficient Double Perovskite EuBaCo2−xO6−δ (x = 0–0.1). Journal of Chemistry. 2017. Vol. 2017, no. 2017, pp.1-5.
https://search.emarefa.net/detail/BIM-1171637
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1171637