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Characterization, Dissolution, and Solubility of Zn-Substituted Hydroxylapatites [(ZnxCa1−x)5(PO4)3OH] at 25°C
Joint Authors
Zhu, Yinian
Zhu, Zongqiang
Zhao, Xin
Liang, Yanpeng
Niu, Yanlong
Lin, Ju
Source
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-13, 13 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-06-15
Country of Publication
Egypt
No. of Pages
13
Main Subjects
Abstract EN
A series of Zn-substituted hydroxylapatites [(ZnxCa1−x)5(PO4)3OH, Zn-Ca-HA] with the Zn/(Zn + Ca) molar ratio (XZn) of 0~0.16 was prepared and characterized, and then the dissolution of the synthesized solids in aqueous solution was investigated by batch experiment.
The results indicated that the aqueous zinc, calcium, and phosphate concentrations greatly depended on the Zn/(Zn + Ca) molar ratio of the Zn-Ca-HA solids (XZn).
For the Zn-Ca-HA dissolution at 25°C with an initial pH of 2.00, the final solution pH increased, while the final solution calcium and phosphate concentrations decreased with the increasing XZn.
The final solution zinc concentrations increased with the increasing XZn when XZn≤0.08 and decreased with the increasing XZn when XZn = 0.08~0.16.
The mean Ksp values for (ZnxCa1−x)5(PO4)3OH at 25°C decreased from 10−57.75 to 10−58.59 with the increasing XZn from 0.00 to 0.08 and then increased from 10–58.59 to 10–56.63 with the increasing XZn from 0.08 to 0.16.
This tendency was consistent with the dependency of the lattice parameter a on XZn.
The corresponding free energies of formation (ΔGfo) increased lineally from −6310.45 kJ/mol to −5979.39 kJ/mol with the increasing XZn from 0.00 to 0.16.
American Psychological Association (APA)
Zhao, Xin& Zhu, Yinian& Zhu, Zongqiang& Liang, Yanpeng& Niu, Yanlong& Lin, Ju. 2017. Characterization, Dissolution, and Solubility of Zn-Substituted Hydroxylapatites [(ZnxCa1−x)5(PO4)3OH] at 25°C. Journal of Chemistry،Vol. 2017, no. 2017, pp.1-13.
https://search.emarefa.net/detail/BIM-1171883
Modern Language Association (MLA)
Zhao, Xin…[et al.]. Characterization, Dissolution, and Solubility of Zn-Substituted Hydroxylapatites [(ZnxCa1−x)5(PO4)3OH] at 25°C. Journal of Chemistry No. 2017 (2017), pp.1-13.
https://search.emarefa.net/detail/BIM-1171883
American Medical Association (AMA)
Zhao, Xin& Zhu, Yinian& Zhu, Zongqiang& Liang, Yanpeng& Niu, Yanlong& Lin, Ju. Characterization, Dissolution, and Solubility of Zn-Substituted Hydroxylapatites [(ZnxCa1−x)5(PO4)3OH] at 25°C. Journal of Chemistry. 2017. Vol. 2017, no. 2017, pp.1-13.
https://search.emarefa.net/detail/BIM-1171883
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1171883