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Direct Benzyl Alcohol and Benzaldehyde Synthesis from Toluene over Keggin-Type Polyoxometalates Catalysts: Kinetic and Mechanistic Studies
Joint Authors
Djaouida, Allam
Sadia, Mansouri
Smaïn, Hocine
Source
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-01-13
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
The catalytic activity of various Keggin polyoxometalate catalysts has been investigated in the gas-phase partial oxidation of toluene to produce benzyl alcohol and benzaldehyde.
The catalyst systems HPMo12O40, HPMo11VO40, FePMo12O40, and PMo11FeO39 were prepared and characterized by FT-IR, UV-visible, SEM, XRD, TGA, and cyclic voltammetry.
The acid/base properties were evaluated using the decomposition of isopropanol.
Catalytic studies were carried under atmospheric pressure and over the temperature range 200°C–350°C, using carbon dioxide as a mild oxidant.
Toluene conversion and product distribution depend mainly on the catalyst composition and operating conditions.
In addition to benzaldehyde, benzyl alcohol is obtained with a high selectivity on the PMo11FeO39 catalyst.
The kinetic data show that the reoxidation of the reduced catalyst is the rate-limiting step for the partial oxidation reaction of toluene.
American Psychological Association (APA)
Djaouida, Allam& Sadia, Mansouri& Smaïn, Hocine. 2019. Direct Benzyl Alcohol and Benzaldehyde Synthesis from Toluene over Keggin-Type Polyoxometalates Catalysts: Kinetic and Mechanistic Studies. Journal of Chemistry،Vol. 2019, no. 2019, pp.1-11.
https://search.emarefa.net/detail/BIM-1172056
Modern Language Association (MLA)
Djaouida, Allam…[et al.]. Direct Benzyl Alcohol and Benzaldehyde Synthesis from Toluene over Keggin-Type Polyoxometalates Catalysts: Kinetic and Mechanistic Studies. Journal of Chemistry No. 2019 (2019), pp.1-11.
https://search.emarefa.net/detail/BIM-1172056
American Medical Association (AMA)
Djaouida, Allam& Sadia, Mansouri& Smaïn, Hocine. Direct Benzyl Alcohol and Benzaldehyde Synthesis from Toluene over Keggin-Type Polyoxometalates Catalysts: Kinetic and Mechanistic Studies. Journal of Chemistry. 2019. Vol. 2019, no. 2019, pp.1-11.
https://search.emarefa.net/detail/BIM-1172056
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1172056