Synthesis, Spectroscopic, and Thermal Investigations of Metal Complexes with Mefenamic Acid
Joint Authors
Kafarska, Karolina
Gacki, Michał
Wolf, Wojciech M.
Source
Issue
Vol. 2017, Issue 2017 (31 Dec. 2017), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2017-12-18
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
The novel metal complexes with empirical formulae M(mef)2·nH2O (where M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II); mef is the mefenamic ligand) were synthesized and characterized by elemental analysis, molar conductance, FTIR-spectroscopy, and thermal decomposition techniques.
All IR spectra revealed absorption bands related to the asymmetric (νas) and symmetric (νs) vibrations of carboxylate group.
The Nakamoto criteria clearly indicate that this group is bonded in a bidentate chelate mode.
The thermal behavior of complexes was studied by TGA methods under non-isothermal condition in air.
Upon heating, all compounds decompose progressively to metal oxides, which are the final products of pyrolysis.
Cu(II), Zn(II), and Cd(II) complexes were also characterized by the coupled TG-FTIR technique, which finally proved the path and gaseous products of thermal decomposition.
Additionally, the coupled TG-MS system was used to determine the principal volatile products of thermolysis and fragmentation processes of Mn(mef)2·3H2O and Co(mef)2·2H2O.
American Psychological Association (APA)
Kafarska, Karolina& Gacki, Michał& Wolf, Wojciech M.. 2017. Synthesis, Spectroscopic, and Thermal Investigations of Metal Complexes with Mefenamic Acid. Journal of Chemistry،Vol. 2017, no. 2017, pp.1-7.
https://search.emarefa.net/detail/BIM-1172122
Modern Language Association (MLA)
Kafarska, Karolina…[et al.]. Synthesis, Spectroscopic, and Thermal Investigations of Metal Complexes with Mefenamic Acid. Journal of Chemistry No. 2017 (2017), pp.1-7.
https://search.emarefa.net/detail/BIM-1172122
American Medical Association (AMA)
Kafarska, Karolina& Gacki, Michał& Wolf, Wojciech M.. Synthesis, Spectroscopic, and Thermal Investigations of Metal Complexes with Mefenamic Acid. Journal of Chemistry. 2017. Vol. 2017, no. 2017, pp.1-7.
https://search.emarefa.net/detail/BIM-1172122
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1172122