Centrosymmetric Binuclear Boron Compounds Derived from Dithiooxamides: Synthesis, Characterization, and Their Photophysical Properties
Joint Authors
Ibarra-Rodríguez, Marisol
Muñoz-Flores, Blanca M.
Cerón, Jesús Lara
Santillán, Rosa
Ochoa, María E.
Waksman, Noemí
Jiménez-Pérez, Víctor M.
Source
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-10-04
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
In this paper, we report the synthesis and characterization of new boron compounds derived from dithiooxamides.
The compounds were characterized by NMR (1H and 13C), UV-vis, fluorescence spectroscopy, and high resolution mass spectrometry.
The crystal structure of the mononuclear boron compound was determined by single-crystal X-ray diffraction analysis.
The photophysical properties of the boron compounds were investigated, and we found moderate fluorescence emission (compound 2 ΦF: 4.07% and compound 4 ΦF: 2.89%).
We also observed that the mononuclear complex presented greater stability.
Compound 4 showed interesting luminescent properties; in solid state, it exhibited an increase in fluorescence by mechanostimuli by changing to a bright red color, and also in solution, it showed a decrease in fluorescence intensity when oxygen and air were supplied to the solution.
American Psychological Association (APA)
Ibarra-Rodríguez, Marisol& Muñoz-Flores, Blanca M.& Cerón, Jesús Lara& Santillán, Rosa& Ochoa, María E.& Waksman, Noemí…[et al.]. 2018. Centrosymmetric Binuclear Boron Compounds Derived from Dithiooxamides: Synthesis, Characterization, and Their Photophysical Properties. Journal of Chemistry،Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1182330
Modern Language Association (MLA)
Ibarra-Rodríguez, Marisol…[et al.]. Centrosymmetric Binuclear Boron Compounds Derived from Dithiooxamides: Synthesis, Characterization, and Their Photophysical Properties. Journal of Chemistry No. 2018 (2018), pp.1-10.
https://search.emarefa.net/detail/BIM-1182330
American Medical Association (AMA)
Ibarra-Rodríguez, Marisol& Muñoz-Flores, Blanca M.& Cerón, Jesús Lara& Santillán, Rosa& Ochoa, María E.& Waksman, Noemí…[et al.]. Centrosymmetric Binuclear Boron Compounds Derived from Dithiooxamides: Synthesis, Characterization, and Their Photophysical Properties. Journal of Chemistry. 2018. Vol. 2018, no. 2018, pp.1-10.
https://search.emarefa.net/detail/BIM-1182330
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1182330
